Synthesis and photovoltaic properties of new Ru(II) complexes for dye-sensitized solar cells

dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.contributor.authorDayan, Osman
dc.contributor.authorOzdemir, Namik
dc.contributor.authorYakuphanoglu, Fahrettin
dc.contributor.authorSerbetci, Zafer
dc.contributor.authorBilici, Ali
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorTercan, Melek
dc.date.accessioned2025-01-27T20:27:12Z
dc.date.available2025-01-27T20:27:12Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractTwo groups Ru(II) complexes, (1A-C and 2A) (A-C = 2,6-bis(2-benzimidazolyl)pyridines, bbpy, with various substituents at 2-, 5-, and 6-positions) have been prepared and applied for dye-sensitized solar cells (DSSC). The compounds were characterized by various techniques. The optical and electrical properties of sensitizers were investigated with UV-Vis absorption spectroscopy and cyclic voltammetry. High power conversion efficiencies up to 5.16%, have been achieved with 2Ae. Current-voltage characteristics of DSSCs clearly affected by the changing of the ligands at sensitizers. Additionally, computational studies show that locations of frontier molecular orbitals are significantly important for power-conversion efficiencies in DSSCs.
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [114Z439]; TUBA; Canakkale Onsekiz Mart University Scientific Research Projects Commission [BAP-2016-1024, FDK-2018-1445]
dc.description.sponsorshipThis research has been supported by The Scientific and Technical Research Council of Turkey (TUBITAK) (Project No: 114Z439), TUBA and Canakkale Onsekiz Mart University Scientific Research Projects Commission (Project Nos: BAP-2016-1024 and FDK-2018-1445).
dc.identifier.doi10.1007/s10854-018-9187-9
dc.identifier.endpage11058
dc.identifier.issn0957-4522
dc.identifier.issn1573-482X
dc.identifier.issue13
dc.identifier.scopus2-s2.0-85048705955
dc.identifier.scopusqualityQ2
dc.identifier.startpage11045
dc.identifier.urihttps://doi.org/10.1007/s10854-018-9187-9
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22617
dc.identifier.volume29
dc.identifier.wosWOS:000435588600037
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Materials Science-Materials in Electronics
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectEffective Core Potentials
dc.subjectCharge-Transfer Sensitizers
dc.subjectPyridine-Based Tridentate
dc.subjectRuthenium(Ii) Complexes
dc.subjectMolecular Calculations
dc.subjectTransfer Hydrogenation
dc.subjectPolypyridyl Complexes
dc.subjectCatalytic-Activity
dc.subjectAncillary Ligands
dc.subject2,6-Bis(Benzimidazol-2-Yl)Pyridine
dc.titleSynthesis and photovoltaic properties of new Ru(II) complexes for dye-sensitized solar cells
dc.typeArticle

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