Synthesis, characterization, optimum reaction conditions, and some polymer-metal complexes of poly(phenoxy-imine)s containing furan ring

Basit Öğe Kaydı
dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorOrta, Ibrahim Erdem
dc.contributor.authorOzdemir, Eyup
dc.contributor.authorSenol, Dilek
dc.date.accessioned2025-01-27T20:43:36Z
dc.date.available2025-01-27T20:43:36Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, Schiff bases containing azomethine (-HC=N-) compounds were synthesized from the condensation reaction of 4-aminophenol and 2-aminophenol and 5-methyl-2-furaldehyde. Orange-colored Schiff bases, 4-[(5-methyl- 2-furyl) methyleneamino] phenol (4MFMAP) and 2-[(5-methyl-2-furyl) methyleneamino] phenol (2MFMAP) turned to poly-4-[(5-methyl-2-furyl) methyleneamino] phenol (P-4MFMAP) and poly-2-[(5-methyl-2-furyl) methyleneamino] phenol (P-2MFMAP) polyazomethine derivatives by NaOCl oxidant in alkaline aqueous medium. In addition, poly-2-[(5-methyl-2-furyl) methyleneamino] phenol cobalt (II) and copper (II) complexes were synthesized. FTIR and NMR measurements for structural analysis of the synthesized compounds, UV-Vis analysis for optical properties, electrical conductivity measurements, and thermal analysis with the TG-DTA techniques were determined. The yield of P-4MFMAP and P-2MFMAP was found to be 84.6% and 78.6 as follows [4MFMAP] = 0.066, [KOH] = 0.198 [NaOCl] = 0.066 mol L-1 at 60 A degrees C for 3 h and [2MFMAP] = 0.066, [KOH] = 0.132 [NaOCl] = 0.066 mol L-1 at 70 A degrees C for 3 h, respectively.
dc.identifier.doi10.1007/s13738-017-1205-y
dc.identifier.endpage46
dc.identifier.issn1735-207X
dc.identifier.issn1735-2428
dc.identifier.issue1
dc.identifier.scopus2-s2.0-85040005747
dc.identifier.scopusqualityQ2
dc.identifier.startpage35
dc.identifier.urihttps://doi.org/10.1007/s13738-017-1205-y
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24291
dc.identifier.volume15
dc.identifier.wosWOS:000419172500005
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of The Iranian Chemical Society
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectSchiff base polymers
dc.subjectPolyphenols
dc.subjectOxidative polycondensation
dc.subjectOptimum reaction conditions
dc.subjectThermal analysis
dc.titleSynthesis, characterization, optimum reaction conditions, and some polymer-metal complexes of poly(phenoxy-imine)s containing furan ring
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu