Palladium(II) and Ruthenium(II) complexes bearing arylsulfonate based ligands: Synthesis, structural characterization and catalytic properties

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dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.contributor.authorKagit, Reyhan
dc.contributor.authorDayan, Osman
dc.contributor.authorOzdemir, Nannk
dc.date.accessioned2025-01-27T20:12:03Z
dc.date.available2025-01-27T20:12:03Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this paper, a series of 4-aminophenyl arylsulfonates (L1-3) and their Schiff bases (L4-6) were synthesized. [Ru(p-cymene)(L1-3)Cl-2] (K1-3), trans-[Pd(L4-6)(2)] (K4-6), and [Ru(p-cymene)(4-aminophenol)Cl-2] (K7) type transition metal complexes have been prepared from the reaction of the appropriate metal salt, L1-6 and 4-aminophenol. All compounds characterized with different techniques like C, H, N analysis, NMR, IR and UV-vis techniques. Solid-state structures of one Ru(II) complex (K1) and one Pd(II) complex (K6) have been determined by single-crystal X-ray diffraction. The complexes K1-7 have been tested as catalysts for the catalytic oxidation of benzyl alcohol to bezaldehyde in the presence of periodic acid (H5IO6). The results show that Ru(II) complexes are more active catalysts than Pd(II) catalysts for this reaction under worked conditions. (C) 2016 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipCanakkale Onsekiz Mart University Scientific Research Projects Commission [FYL-2014-180]
dc.description.sponsorshipThis research has been supported by Canakkale Onsekiz Mart University Scientific Research Projects Commission (Project No: FYL-2014-180).
dc.identifier.doi10.1016/j.poly.2016.06.044
dc.identifier.endpage512
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84978811152
dc.identifier.scopusqualityQ2
dc.identifier.startpage504
dc.identifier.urihttps://doi.org/10.1016/j.poly.2016.06.044
dc.identifier.urihttps://hdl.handle.net/20.500.12428/20829
dc.identifier.volume117
dc.identifier.wosWOS:000384384500059
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPd(II) complexes
dc.subjectRu(II) complexes
dc.subjectOxidation of benzyl alcohol
dc.subjectSchiff bases ligands
dc.subjectArylsulfonate ligands
dc.titlePalladium(II) and Ruthenium(II) complexes bearing arylsulfonate based ligands: Synthesis, structural characterization and catalytic properties
dc.typeArticle

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