The effect of the oxidant used during polymerization on the solid-state decomposition kinetics of poly(4-methyl catechol)

Basit Öğe Kaydı
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridDoğan, Fatih / 0000-0002-3088-886X
dc.authoridDoğan, Fatih / 0000-0001-5844-8893
dc.contributor.authorDoğan, Fatih
dc.contributor.authorTopallar, Harika
dc.contributor.authorKaya, İsmet
dc.contributor.authorYürekli, Mehmet
dc.date.accessioned2025-01-27T20:47:34Z
dc.date.available2025-01-27T20:47:34Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractHerein, the oxidative polymerization of 4-methyl catechol using different oxidants including NaOCl, H2O2, and air were reported. Potassium hydroxide solution was used as the reaction solvent and polymerization studies were carried out between 323 and 363 K. Optimum reaction conditions of the polymerization were established and NaOCl was found as the most active oxidant. The structure and characterization of the polymer using FT-IR, ultraviolet-visible (UV-Vis), H-1-NMR, C-13-NMR, thermogravimetry and size exclusion chromatography were confirmed. In addition, the relationship between molar mass distribution of polymer and kinetics parameters such as activation energy, pre-exponential factor of decomposition process was investigated. For this purpose, methods based on multiple heating rates such as Flynn-Wall-Ozawa, Friedman, Tang, Kissinger-Akahira-Sunose, and Kissinger were used. The results obtained show that activation energy increased with an increase of molar mass.
dc.identifier.doi10.1007/s10973-012-2517-x
dc.identifier.endpage1522
dc.identifier.issn1388-6150
dc.identifier.issue2
dc.identifier.scopus2-s2.0-84872489058
dc.identifier.scopusqualityQ1
dc.identifier.startpage1515
dc.identifier.urihttps://doi.org/10.1007/s10973-012-2517-x
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24965
dc.identifier.volume111
dc.identifier.wosWOS:000313409700066
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectOxidative polymerization
dc.subjectThermal analysis
dc.subjectNon-isothermal decomposition kinetics
dc.titleThe effect of the oxidant used during polymerization on the solid-state decomposition kinetics of poly(4-methyl catechol)
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
Ismet Kaya_Makale.pdf
Boyut:
659.56 KB
Biçim:
Adobe Portable Document Format
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Bölümü Koleksiyonu
Matematik ve Fen Bilimleri Eğitimi Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu