Peroxidase/H2O2 catalyzed oxidative oligomerization of 1-aminopyrene

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dc.authoridTemizkan Özdamar, Kevser / 0000-0001-7740-3252
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridBilici, Ali / 0000-0002-1377-5580
dc.authoridTezel, Ruhiye Nilay / 0000-0001-6113-6057
dc.authoridDoğan, Fatih / 0000-0002-3088-886X / 0000-0001-5844-8893
dc.contributor.authorKaya, İsmet
dc.contributor.authorBilici, Ali
dc.contributor.authorTezel, Ruhiye Nilay
dc.contributor.authorTemizkan, Kevser
dc.contributor.authorDoğan, Fatih
dc.date.accessioned2025-01-27T21:03:41Z
dc.date.available2025-01-27T21:03:41Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA new florescent oligo(aminopyrene) (OAP) was successfully synthesized by enzymatic approach. For this, H2O2 and Horse Radish peroxidase (HRP) were used as catalyst and oxidant, respectively. The structures of monomer and oxidation product were confirmed by NMR, FT-IR and UV-Vis measurements. The oxidation product was characterized by gel permeation chromatography (GPC), thermogravimetry (TG), differential scanning calorimetry (DSC), cyclic voltammetry (CV), photoluminescence (PL) and scanning electron microscopy (SEM) analyses. OAP was soluble in a wide range of organic solvents. UV-Vis spectrum of the OAP showed a dramatic red shift compared to that of the monomer. The optical and electrochemical band gaps of OAP were found to be 1.65 and 1.56 eV, respectively. OAP emitted turquoise color in THF and green color in toluene. SEM observations indicated the presence of a heterogeneous cauliflower like morphology.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [113Z562]
dc.description.sponsorshipThe authors thank the following source for financial support: The Scientific and Technological Research Council of Turkey (TUBITAK) with project Nu.: 113Z562.
dc.identifier.doi10.1080/10601325.2017.1282698
dc.identifier.endpage248
dc.identifier.issn1060-1325
dc.identifier.issn1520-5738
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85015739391
dc.identifier.scopusqualityQ2
dc.identifier.startpage243
dc.identifier.urihttps://doi.org/10.1080/10601325.2017.1282698
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27405
dc.identifier.volume54
dc.identifier.wosWOS:000396841700007
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofJournal of Macromolecular Science Part A-Pure and Applied Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subject1-Aminopyrene
dc.subjectenzymatic polymerization
dc.subjectHRP
dc.subjectoxidative polymerization
dc.subjectphotoluminescence
dc.titlePeroxidase/H2O2 catalyzed oxidative oligomerization of 1-aminopyrene
dc.typeArticle

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