P(2-VP) supported Ru(II) material as catalyst for H2 production from the methanolysis of NaBH4

dc.authoridOral, Ayhan/0000-0003-4965-8754
dc.authoridKaracan Yeldir, Elif/0000-0001-8638-1198
dc.authoriddayan, osman/0000-0002-0764-1965
dc.contributor.authorTercan, Melek
dc.contributor.authorKaracan Yeldir, Elif
dc.contributor.authorDayan, Osman
dc.contributor.authorOral, Ayhan
dc.date.accessioned2025-01-27T20:38:40Z
dc.date.available2025-01-27T20:38:40Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractExisting energy resources are not sufficient to meet the energy needs of the increasing world population so the need for clean and renewable energy systems is increasing day after day. Hydrogen is a good alternative energy source because of its clean by-products and high energy capacity. Studies on hydrogen storage systems that provide instant hydrogen production in the literature are of great interest. In this study, poly-2-vinylpyridine (p(2-VP)) polymer was prepared by photopolymerization method and reacted with 2,6-bis(2-benzimidazolyl)pyridine ligand containing Ru(II) complex to give p(2-VP) supported Ru(II) material. The synthesized Ru(II) complex was characterized by FT-IR, UV-Vis and H-1-NMR spectroscopic techniques. Also the p(2-VP) polymer was characterized by FT-IR spectroscopy. The obtained p(2-VP) supported Ru(II) material was used as catalyst in hydrogen generation from NaBH4 metanolysis reaction and the reaction kinetic was investigated.
dc.identifier.doi10.1080/24701556.2020.1749077
dc.identifier.endpage1352
dc.identifier.issn2470-1556
dc.identifier.issn2470-1564
dc.identifier.issue12
dc.identifier.scopus2-s2.0-85084323212
dc.identifier.scopusqualityQ2
dc.identifier.startpage1343
dc.identifier.urihttps://doi.org/10.1080/24701556.2020.1749077
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23703
dc.identifier.volume50
dc.identifier.wosWOS:000533219600001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofInorganic and Nano-Metal Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectHydrogen energy
dc.subjectruthenium
dc.subjectbenzimidazole type ligand
dc.subjectp(2-VP) polymer
dc.subjectmethanolysis
dc.titleP(2-VP) supported Ru(II) material as catalyst for H2 production from the methanolysis of NaBH4
dc.typeArticle

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