Synthesis, characterisation, photophysical and photochemical properties of free-base tetra-(5-chloro-2-(2,4-dichlorophenoxy) phenoxy)phthalocyanine and respective zinc(II) and lead(II) complexes

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dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.authoridAKCAY, Hakki Turker/0000-0002-8502-9608
dc.contributor.authorDemirbas, Umit
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorAkcay, Hakki Turker
dc.contributor.authorBarut, Burak
dc.contributor.authorDurmus, Mahmut
dc.contributor.authorKantekin, Halit
dc.date.accessioned2025-01-27T21:01:56Z
dc.date.available2025-01-27T21:01:56Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, novel peripherally tetra-(5-chloro-2-(2,4-dichlorophenoxy)phenol) substituted metal-free (4), zinc(II) (5) and lead(II) (6) phthalocyanine derivatives were synthesised. The novel phthalocyanines (4-6) were characterised by general spectroscopic methods such as IR, H-1 NMR, UV-vis, mass spectrometry and elemental analysis. Once the solubilities of the compounds were investigated, it was noticed that they have excellent solubility and did not tend to aggregation behaviour in common solvents. The photophysical and photochemical properties of novel phthalocyanines (4-6) were investigated in dimethysulfoxide. The effects of substituted 5-chloro-2-(2,4-dichlorophenoxy)phenoxy group and central metal ion [zinc(II)/lead(II)] on photophysical and photochemical properties of the novel phthalocyanines have also been examined, and the results were compared with unsubstituted zinc (II) phthalocyanine. According to photophysical and photochemical investigation results, it was observed that the novel phthalocyanines (4-6) have a potential for PDT application. (C) 2016 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.synthmet.2016.12.004
dc.identifier.endpage171
dc.identifier.issn0379-6779
dc.identifier.scopus2-s2.0-85006173733
dc.identifier.scopusqualityQ1
dc.identifier.startpage166
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2016.12.004
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27236
dc.identifier.volume223
dc.identifier.wosWOS:000392681600021
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectSynthesis
dc.subjectPhthalocyanine
dc.subject5-Chloro-2-(2,4-dichlorophenoxy)phenol
dc.subjectPhotosensitiser
dc.subjectPhotophysical
dc.subjectPhotochemical
dc.titleSynthesis, characterisation, photophysical and photochemical properties of free-base tetra-(5-chloro-2-(2,4-dichlorophenoxy) phenoxy)phthalocyanine and respective zinc(II) and lead(II) complexes
dc.typeArticle

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