Asymmetric Reduction of Monoketo Hexadecanoic Acid Methyl Esters

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dc.authoridTURKER, GULEN/0000-0002-7554-1544
dc.contributor.authorTurker, Gulen
dc.contributor.authorYusufoglu, Ayse
dc.date.accessioned2025-01-27T21:21:44Z
dc.date.available2025-01-27T21:21:44Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractMethyl 2-,3-,6-,8-,14- and 15-keto hexadecanoates were reduced by using NaBH4 in presence of 1,2;5,6-di-O-isopropilydene-D-glucofuranose [DIPGH], R(+)-1,1'-binaphthyl-2,2'-diol [RBND] and pivalic acid [PA]. The reduction of 2- and 3-keto esters in the presence of (+)-1,1'-binaphthyl-2,2'-diol results in considerably higher stereoselectivities (95 % ee). Enantiometric excess (ee %) was determined by H-1 and C-13 NMR analyses using a shift reagent, Eu(tfc)(3).
dc.description.sponsorshipResearch Fund of the University of Istanbul [T-190/06032003]
dc.description.sponsorshipThis work was supported by the Research Fund of the University of Istanbul (Project No.: T-190/06032003).
dc.identifier.endpage1535
dc.identifier.issn0970-7077
dc.identifier.issn0975-427X
dc.identifier.issue3
dc.identifier.scopus2-s2.0-84875182054
dc.identifier.scopusqualityQ4
dc.identifier.startpage1531
dc.identifier.urihttps://hdl.handle.net/20.500.12428/29049
dc.identifier.volume25
dc.identifier.wosWOS:000312621400080
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAsian Journal Of Chemistry
dc.relation.ispartofAsian Journal of Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectReduction
dc.subjectEnantiometric excess
dc.subjectKeto hexadecanoates
dc.titleAsymmetric Reduction of Monoketo Hexadecanoic Acid Methyl Esters
dc.typeArticle

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