Kinetic Evaluation and Catalytic Efficiency of Sebacic Acid as a Novel Catalyst in Hydrogen Generation via NaBH4 Alcoholysis Reactions
| dc.authorid | GURDAL, SAVAS/0000-0002-1149-4371 | |
| dc.contributor.author | Gurdal, Savas | |
| dc.date.accessioned | 2025-01-27T20:59:35Z | |
| dc.date.available | 2025-01-27T20:59:35Z | |
| dc.date.issued | 2024 | |
| dc.department | Çanakkale Onsekiz Mart Üniversitesi | |
| dc.description.abstract | This study explores the use of sebacic acid, a catalyst not previously examined in the literature, for hydrogen production from NaBH4 through methanolysis and ethanolysis reactions. Solutions of sebacic acid with concentrations ranging from 0.1 M to 0.4 M were prepared and tested. At a concentration of 0.3 M, 90% of the hydrogen from a 0.33 M NaBH4 solution was released within 3 s, and full release was achieved in 4 s. Hydrogen production rates reached 4500 mL/min for ethanolysis and 4845 mL/min for methanolysis, with methanolysis reactions proving faster. The activation energies for methanolysis and ethanolysis were calculated as 7.17 kJ/mol and 52.3 kJ/mol, respectively. These results demonstrate that sebacic acid enables rapid and efficient hydrogen production, offering a new approach that significantly advances current hydrogen production methods. | |
| dc.identifier.doi | 10.3390/catal14090644 | |
| dc.identifier.issn | 2073-4344 | |
| dc.identifier.issue | 9 | |
| dc.identifier.scopus | 2-s2.0-85205048806 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.uri | https://doi.org/10.3390/catal14090644 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12428/26733 | |
| dc.identifier.volume | 14 | |
| dc.identifier.wos | WOS:001326432400001 | |
| dc.identifier.wosquality | N/A | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | |
| dc.publisher | Mdpi | |
| dc.relation.ispartof | Catalysts | |
| dc.relation.publicationcategory | info:eu-repo/semantics/openAccess | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.snmz | KA_WoS_20250125 | |
| dc.subject | sebacic acid | |
| dc.subject | sodium borohydride | |
| dc.subject | ethanolysis | |
| dc.subject | methanolysis | |
| dc.subject | hydrogen production | |
| dc.title | Kinetic Evaluation and Catalytic Efficiency of Sebacic Acid as a Novel Catalyst in Hydrogen Generation via NaBH4 Alcoholysis Reactions | |
| dc.type | Article |
