Kinetic Evaluation and Catalytic Efficiency of Sebacic Acid as a Novel Catalyst in Hydrogen Generation via NaBH4 Alcoholysis Reactions

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dc.authoridGürdal, Savaş / 0000-0002-1149-4371
dc.contributor.authorGürdal, Savaş
dc.date.accessioned2025-01-27T20:59:35Z
dc.date.available2025-01-27T20:59:35Z
dc.date.issued2024
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis study explores the use of sebacic acid, a catalyst not previously examined in the literature, for hydrogen production from NaBH4 through methanolysis and ethanolysis reactions. Solutions of sebacic acid with concentrations ranging from 0.1 M to 0.4 M were prepared and tested. At a concentration of 0.3 M, 90% of the hydrogen from a 0.33 M NaBH4 solution was released within 3 s, and full release was achieved in 4 s. Hydrogen production rates reached 4500 mL/min for ethanolysis and 4845 mL/min for methanolysis, with methanolysis reactions proving faster. The activation energies for methanolysis and ethanolysis were calculated as 7.17 kJ/mol and 52.3 kJ/mol, respectively. These results demonstrate that sebacic acid enables rapid and efficient hydrogen production, offering a new approach that significantly advances current hydrogen production methods.
dc.identifier.doi10.3390/catal14090644
dc.identifier.issn2073-4344
dc.identifier.issue9
dc.identifier.scopus2-s2.0-85205048806
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.3390/catal14090644
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26733
dc.identifier.volume14
dc.identifier.wosWOS:001326432400001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMdpi
dc.relation.ispartofCatalysts
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectsebacic acid
dc.subjectsodium borohydride
dc.subjectethanolysis
dc.subjectmethanolysis
dc.subjecthydrogen production
dc.titleKinetic Evaluation and Catalytic Efficiency of Sebacic Acid as a Novel Catalyst in Hydrogen Generation via NaBH4 Alcoholysis Reactions
dc.typeArticle

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