Benign Preparation of Metal-Organic Frameworks of Trimesic Acid and Cu, Co or Ni for Potential Sensor Applications

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dc.authoridDemirci, Şahin / 0000-0001-7083-1481
dc.authoridSel, Kıvanç / 0000-0002-4623-5206
dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.authoridMeydan, Engin / 0000-0002-1860-1715
dc.authoridYıldız, Sema / 0000-0003-4760-164X
dc.authoridÖztürk, Ömer Faruk / 0000-0002-9244-6805
dc.contributor.authorSel, Kıvanç
dc.contributor.authorDemirci, Şahin
dc.contributor.authorMeydan, Engin
dc.contributor.authorYıldız, Sema
dc.contributor.authorÖztürk, Ömer Faruk
dc.contributor.authorAl-Lohedan, Hamad
dc.contributor.authorŞahiner, Nurettin
dc.date.accessioned2025-01-27T21:00:09Z
dc.date.available2025-01-27T21:00:09Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractMetal-organic frameworks (MOFs) have been constructed using trimesic acid (TMA) as organic linker and Co(II), Ni(II) or Cu(II) metal ions from their corresponding aqueous chloride salts at room temperature. The prepared TMA-M (M: Co, Ni, and Cu) MOFs have been characterized in terms of their porosity and optical, thermal, electrical, and structural properties. The prepared MOFs were characterized in terms of their porosity through Brunauer-Emmett-Teller measurements, yielding a value of 330 m(2)/g for the TMA-Cu MOF. Structural analysis and thermal characterization of the prepared MOFs were done by using Fourier-transform infrared (FT-IR) spectroscopy, x-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA), respectively. The optical properties were analyzed by fluorescence spectroscopy. Additionally, TMA-M MOF disks were prepared and their conductivities determined by room-temperature I-V measurements. The conductivity of the TMA-M MOFs was calculated to be between 7.97 x 10(-7) S/cm and 5.39 x 10(-9) S/cm.
dc.description.sponsorshipKing Saud University
dc.description.sponsorshipThe project was supported by King Saud University, Deanship of Scientific Research, Research Chair.
dc.identifier.doi10.1007/s11664-014-3444-3
dc.identifier.endpage143
dc.identifier.issn0361-5235
dc.identifier.issn1543-186X
dc.identifier.issue1
dc.identifier.scopus2-s2.0-84919713238
dc.identifier.scopusqualityQ2
dc.identifier.startpage136
dc.identifier.urihttps://doi.org/10.1007/s11664-014-3444-3
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26951
dc.identifier.volume44
dc.identifier.wosWOS:000346703800018
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Electronic Materials
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectTMA-M metal-organic frameworks
dc.subjectMOFs
dc.subjectporous materials
dc.subjectconductive MOFs
dc.titleBenign Preparation of Metal-Organic Frameworks of Trimesic Acid and Cu, Co or Ni for Potential Sensor Applications
dc.typeArticle

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