Synthesis of ruthenium(II) complexes derived from reduced imine ligands: As catalysts for transfer hydrogenation of ketones

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dc.authoriddayan, serkan/0000-0003-4171-7297
dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridKAYACI, Nilgun/0000-0002-7988-8668
dc.contributor.authorDayan, Serkan
dc.contributor.authorKayaci, Nilgun
dc.contributor.authorKalaycioglu, Nilgun Ozpozan
dc.contributor.authorDayan, Osman
dc.contributor.authorOzturk, Esra Circir
dc.date.accessioned2025-01-27T20:56:13Z
dc.date.available2025-01-27T20:56:13Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractN-[2-(benzylamino)phenyl]benzenesulfonamide derivatives (1-6) were successfully synthesized by the reaction of imine ligands derived from various N-(2-aminophenyl)benzenesulfonamides and NaBH4. Then, a series of N-coordinate Ru(II) arene complexes 7-12 were prepared from the reaction of [RuCl2(p-cymene)](2) with 1-6. The synthesized compounds were characterized by different methods such as NMR, FT-IR, and elemental analysis. 7-12 were used as catalysts for the transfer hydrogenation (TH) of ketones. At the same time, the effect of various bases such as NaOH, KOH, KOBut and Et3N as organic base were investigated in TH of ketones by 2-propanol as the hydrogen source. 7-12 showed good catalytic activity and so the effects of the different groups were also examined. Crown Copyright (c) 2013 Published by Elsevier B.V. All rights reserved.
dc.description.sponsorshipErciyes University (ERUBAP) [FBY-11-3783]
dc.description.sponsorshipWe acknowledge the financial support granted by Erciyes University (ERUBAP), (FBY-11-3783, ID: 3783).
dc.identifier.doi10.1016/j.ica.2013.03.004
dc.identifier.endpage113
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84877058247
dc.identifier.scopusqualityQ2
dc.identifier.startpage107
dc.identifier.urihttps://doi.org/10.1016/j.ica.2013.03.004
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26340
dc.identifier.volume401
dc.identifier.wosWOS:000319123700016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectTransfer hydrogenation
dc.subjectRu(II) complexes
dc.subjectSulfonamide
dc.subjectImine
dc.titleSynthesis of ruthenium(II) complexes derived from reduced imine ligands: As catalysts for transfer hydrogenation of ketones
dc.typeArticle

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