Synthesis and Characterization of Poly(L-Lactic acid)/Clay Nanocomposite via Metal-Free Process

dc.authoridOral, Ayhan/0000-0003-4965-8754
dc.authoridBasaran, Ihsan/0000-0002-7824-8968
dc.contributor.authorBasaran, Ihsan
dc.contributor.authorOral, Ayhan
dc.date.accessioned2025-01-27T20:44:07Z
dc.date.available2025-01-27T20:44:07Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractBiopolymer nanocomposite was synthesized using metal-free catalyst which is Montmorillonite-K10 as organic filler and acid catalyst for polymerization of L-Lactic acid. To evaluate the effect of Montmorillonite onto polymer properties, 1, 3 and 5% clay were used. Products were characterized using X-ray diffraction and transmission electron microscopy. Thermal parameters of products were investigated via differential scanning calorimeter and thermo-gravimetric analyzer. Thermal stability, degree of crystallinity, temperatures for glass transition, crystallization and melting of the nanocomposites were studied. Effect of clay onto molecular weight was investigated via gel permeation chromatography. It was found that properties of polymer were influenced by addition of clay.
dc.description.sponsorshipScientific and Technological Research Counsil of Turkey (TUBITAK) [109 T575]; TUBITAK; Arcelik Inc.
dc.description.sponsorshipThis work was financially supported by The Scientific and Technological Research Counsil of Turkey (TUBITAK) (109 T575). I would like to thank both TUBITAK for the financial support and Arcelik Inc. for support.
dc.identifier.doi10.1080/03602559.2013.814146
dc.identifier.endpage1276
dc.identifier.issn0360-2559
dc.identifier.issue12
dc.identifier.scopus2-s2.0-84884237781
dc.identifier.scopusqualityN/A
dc.identifier.startpage1271
dc.identifier.urihttps://doi.org/10.1080/03602559.2013.814146
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24481
dc.identifier.volume52
dc.identifier.wosWOS:000323999700014
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofPolymer-Plastics Technology and Engineering
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectBio-nanocomposite
dc.subjectIn situ polymerization
dc.subjectMetal-free
dc.subjectMontmorillonite-K10
dc.subjectPoly(L-lactic acid)
dc.subjectThermal properties
dc.titleSynthesis and Characterization of Poly(L-Lactic acid)/Clay Nanocomposite via Metal-Free Process
dc.typeArticle

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