Synthesis and characterization of cobalt nanoparticles containing anionic polymer hydrogel nanocomposite catalysts for fast reduction of nitrocompounds in water

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dc.authorid0000-0003-0120-530Xen_US
dc.authorscopusid6602001525en_US
dc.authorwosid-en_US
dc.contributor.authorJabeen, Nusrat
dc.contributor.authorFarooqi, Zahoor H.
dc.contributor.authorShah, Attaullah
dc.contributor.authorAli, Abid
dc.contributor.authorKhurram, Muhammad
dc.contributor.authorMahmood, Khalid
dc.contributor.authorŞahiner, Nurettin
dc.contributor.authorAjmal, Muhammad
dc.date.accessioned2022-07-07T07:39:31Z
dc.date.available2022-07-07T07:39:31Z
dc.date.issued2021en_US
dc.departmentFakülteler, Fen Fakültesi, Kimya Bölümü
dc.description.abstractDesign and development of hydrogel based metal nanocomposites is of vital signifcance in the feld of industrial waste management. In this study, the synthesis of poly (N-isopropylacrylamide-co-2-Acrylamido-2-methylpropane sulfonic acid) hydrogel and embedment of cobalt nanoparticles in the prepared hydrogel was demonstrated followed by the evaluation of catalytic potential of the as-prepared cobalt nanoparticles-hydrogel nanocomposite. The prepared hydrogel and corresponding nanocomposite were characterized by Fourier Transform Infrared (FTIR) spectroscopy to identify functional groups, Energy Dispersive X-ray (EDX) and Inductively Coupled Plasma—Optical Emission Spectrometry (ICP-OES) analysis to confrm the presence of cobalt, and Transmission Electron Microscopy (TEM) to assess the spatial morphology of cobalt nanoparticles. The prepared hydrogel showed absorption of water via non-Fickian mechanism, resulting in swelling as much as 69 times of its dry weight. The nanoparticles were found to be spherical in shape and having diameters around 25 nm. The potential catalytic properties of the cobalt nanoparticles-hydrogel nanocomposite were assessed while reducing 4-nitrophenol, 2-nitrophenol, 4-nitroaniline, and 2-nitroaniline to their corresponding amino compounds. The catalytic reactions were performed under varying temperatures and catalyst quantities, besides the catalyst was also subjected to rigorous repeated usage to evaluate its recycling potential. The thermodynamic parameters such as activation energy, activation entropy change, and activation enthalpy change were also calculated. The catalyst was found to be more efective in reducing 4-nitrophenol with a maximum rate constant of 4.67 min−1. A gradual decline in catalytic reduction rate was observed when the same catalyst was repeatedly used for fve consecutive cycles.en_US
dc.identifier.citationJabeen, N., Farooqi, Z. H., Shah, A., Ali, A., Khurram, M., Mahmood, K., … Ajmal, M. (2021). Synthesis and characterization of cobalt nanoparticles containing anionic polymer hydrogel nanocomposite catalysts for fast reduction of nitrocompounds in water. Journal of Porous Materials, 28(5), 1563–1576. https://doi.org/10.1007/s10934-021-01105-0en_US
dc.identifier.doi10.1007/s10934-021-01105-0
dc.identifier.endpage1576en_US
dc.identifier.issn1380-2224
dc.identifier.issn1573-4854
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85107961345
dc.identifier.startpage1563en_US
dc.identifier.urihttps://doi.org/10.1007/s10934-021-01105-0
dc.identifier.urihttps://hdl.handle.net/20.500.12428/3618
dc.identifier.volume28en_US
dc.identifier.wosWOS:000661810100001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorŞahiner, Nurettin
dc.language.isoen
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Porous Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHydrogelsen_US
dc.subjectNanocompositesen_US
dc.subjectCatalysisen_US
dc.subjectActivation Energyen_US
dc.titleSynthesis and characterization of cobalt nanoparticles containing anionic polymer hydrogel nanocomposite catalysts for fast reduction of nitrocompounds in water
dc.typeArticle

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