Synthesis and Characterization of Imine Polymers Containing Aliphatic and Aromatic Groups and Some of Schiff Base-Metal Complexes

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorUysal, Seçil
dc.date.accessioned2025-01-27T20:27:19Z
dc.date.available2025-01-27T20:27:19Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, the oxidative polycondensation reaction conditions of 2,2'-[(2,5-dichloro-1,4-phenylene) bisnitrilomethylylidene]diphenol (DCPMDP) were studied between 40 and 90 degrees C using different times and concentrations in the alkaline medium to determine effect on the yield of these parameters. Polymerization of 2,2'-piperazine-1,4-diylbis[propane-3,1-diylnitrilomethy-lylidene] diphenol (PDMDP) was performed at two steps with graft polycondensation method. Additionally, seven different metal complexes were also synthesized from PDMDP with some metal salts. The structures of the compounds were confirmed by UV-vis, FT-IR, (1)H and (13)C NMR spectroscopy analyses. The characterization was made by TG-DTA, size exclusion chromatography (SEC), elemental analysis, and solubility tests. HOMO-LUMO energy levels and electrochemical band (E(g)(')) gaps were determined from cyclic voltammetry (CV) measurements. Also, optical band (E(g)) gaps were calculated from UV-vis measurements. Electrical conductivity of doped and undoped monomer and oligomer were measured by four-point probe technique using an electrometer. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 120: 3325-3336, 2011
dc.identifier.doi10.1002/app.33515
dc.identifier.endpage3336
dc.identifier.issn0021-8995
dc.identifier.issue6
dc.identifier.scopus2-s2.0-79952497381
dc.identifier.scopusqualityQ2
dc.identifier.startpage3325
dc.identifier.urihttps://doi.org/10.1002/app.33515
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22655
dc.identifier.volume120
dc.identifier.wosWOS:000288393100025
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-Blackwell
dc.relation.ispartofJournal of Applied Polymer Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectoxidative polycondensation
dc.subjectpolyimines
dc.subjectelectrical conductivity
dc.subjectthermal analysis
dc.titleSynthesis and Characterization of Imine Polymers Containing Aliphatic and Aromatic Groups and Some of Schiff Base-Metal Complexes
dc.typeArticle

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