Synthesis of a cationic ruthenium(ii) complex and its non-enzymatic glucose-sensing properties
Yükleniyor...
Tarih
2023
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Society of Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The new cationic ruthenium(ii) complex (2) was synthesized via the reaction of N,N′-[1,1′-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene)]bis(2-ethyl-6-methylaniline) and [RuCl2(p-cymene)]2, and it was fully characterized using NMR, FT-IR, single-crystal X-ray diffraction, ESI-MS, UV-vis, CV and thermal analysis methods; theoretical computational characterizations and geometric parameters for 2 were also carried out via quantum chemical calculations using the density functional theory (DFT) method. In addition, the synthesized Ru(ii) complex (2) was immobilized on fabricated RGO-TiO2@FTO to evaluate its non-enzymatic biosensing properties, and the sensing properties of the resulting Ru(ii)-RGO-TiO2@FTO electrode were recorded. As a glucose-sensing model, at an applied potential of +0.34 V, the Ru(ii)-RGO-TiO2@FTO electrode presented a moderately good sensitivity of 62.69 μA mM−1 cm−1. Various modifications of Ru(ii)-RGO-TiO2@FTO-type electrodes, such as the metal complex, and material types and ratios, will enable the design of future biosensor devices with improved performance.
Açıklama
Anahtar Kelimeler
Synthesis (chemical), Quantum chemistry, Synthesis of a cationic ruthenium(ii) complex
Kaynak
New Journal of Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Cilt
47
Sayı
21
Künye
Dayan, S., Özdemir, N., Erdener, D., Dayan, O., & Çetinkaya, B. (2023). Synthesis of a cationic ruthenium(II) complex and its non-enzymatic glucose-sensing properties. New Journal of Chemistry, 47(21), 10187–10194. https://doi.org/10.1039/D2NJ05470A
