Synthesis of Poly(cyclohexene oxide)-Montmorillonite Nanocomposite via In Situ Photoinitiated Cationic Polymerization with Bifunctional Clay

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dc.authoridOral, Ayhan/0000-0003-4965-8754
dc.contributor.authorBayram, Isil
dc.contributor.authorOral, Ayhan
dc.contributor.authorSirin, Kamil
dc.date.accessioned2025-01-27T20:52:10Z
dc.date.available2025-01-27T20:52:10Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPoly(cyclohexene oxide) (PCHO)/clay nanocomposites were prepared by means of in situ photoinitiated cationic polymerization with initiator moieties immobilized within the silicate galleries of the clay particles. Diphenyliodonium molecules were intercalated via cation exchange process between Cloisite Ca and diphenyliodonium. The polymerization of CHO through the interlayer galleries of the clay can provide a homogenous distribution of the clay layers in the polymer matrix in nanosize and results in the formation of PCHO/clay nanocomposites. The rates of clay loadings were changed to 1%, 3%, and 5% so as to investigate the effect of clay and initiator amount on polymer. X-ray diffraction (XRD) spectroscopy, thermogravimetric analysis (TGA), and transmission electron microscopy (TEM) methods were used for the characterization of modified clay and nanocomposite materials. Thermal stability of PCHO/MMT nanocomposites was also studied by both differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).
dc.description.sponsorshipCanakkale Onsekiz Mart University
dc.description.sponsorshipThis research was supported by Canakkale Onsekiz Mart University. The authors would like to thank Canakkale Onsekiz Mart University for the financial support.
dc.identifier.doi10.1155/2013/617498
dc.identifier.issn2090-9063
dc.identifier.issn2090-9071
dc.identifier.scopus2-s2.0-84880153600
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1155/2013/617498
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25681
dc.identifier.volume2013
dc.identifier.wosWOS:000321641900001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherHindawi Ltd
dc.relation.ispartofJournal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectPolymer/Layered Silicate Nanocomposites
dc.subjectThermomechanical Properties
dc.subjectConductivity
dc.titleSynthesis of Poly(cyclohexene oxide)-Montmorillonite Nanocomposite via In Situ Photoinitiated Cationic Polymerization with Bifunctional Clay
dc.typeArticle

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