Synthesis and Characterizations of Poly(phenoxy-Imine)s via Catalyzed Oxidative Polymerization by Polymer-Metal Complex

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorSenol, Dilek
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:27:30Z
dc.date.available2025-01-27T20:27:30Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, Schiff base was synthesized from the condensation reaction of 3,5-diaminobenzoic acid, 4,4-diaminobenzanilide, vanillin with 4-hydroxybenzaldehyde. Then, Schiff bases polymers were synthesized via oxidative polycondensation method in the presence of catalyst (polymer-metal complex) in organic solvent. Schiff base polymers were compared to the ones which were previously polymerized without catalyst. The structures of synthesized monomers and polymers were determined by FT-IR, NMR, SEC and SEM analyses; the optical characteristics by UV-Vis and fluorescence spectroscopy methods, solid state conductivity measurements by four-point probe technique, the electrochemical properties by CV analysis, thermal behaviors by TG-DTA and DSC measurements were effectively determined. Depending on the synthetic method of polymer, structural change, optical, electrochemical and thermal differences were measured. Availability of these polymers in the production of light-emitting diode, electronic-optoelectronic and thermal resistant materials was explored.
dc.identifier.doi10.1007/s13369-016-2390-1
dc.identifier.endpage2396
dc.identifier.issn2193-567X
dc.identifier.issn2191-4281
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85019700968
dc.identifier.scopusqualityQ1
dc.identifier.startpage2381
dc.identifier.urihttps://doi.org/10.1007/s13369-016-2390-1
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22705
dc.identifier.volume42
dc.identifier.wosWOS:000402081500020
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Heidelberg
dc.relation.ispartofArabian Journal For Science and Engineering
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPoly(phenoxy-imine)s
dc.subjectConductivity
dc.subjectThermal analysis
dc.subjectEmission spectra
dc.subjectBand gap
dc.titleSynthesis and Characterizations of Poly(phenoxy-Imine)s via Catalyzed Oxidative Polymerization by Polymer-Metal Complex
dc.typeArticle

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