A new phosphazene derivative, spiro-N3P3[(O2C12H8)2(OC6H6N-3)2], and its Ru(II) complex: Syntheses, crystal structure, catalytic activity and antimicrobial activity studies

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dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.contributor.authorCirali, Digdem Erdener
dc.contributor.authorDayan, Osman
dc.contributor.authorOzdemir, Namik
dc.contributor.authorHacloglu, Nurcihan
dc.date.accessioned2025-01-27T20:14:39Z
dc.date.available2025-01-27T20:14:39Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA cyclotriphosphazene ligand containing the spirocyclic 2,2'-dioxybiphenyl group and 2-methy1-3-pyridyloxy moieties was synthesized. A Ru(11) complex was prepared from the reaction of [RuCl2(p-cymene)](2) with this ligand. The structures of the ligand and the Ru(II) complex were characterized by FT-IR, H-1 and P-31 NMR spectroscopy. In addition, the molecular structure of the ligand was confirmed by X-ray crystallography. The Ru(II) complex was used as catalyst for the Catalytic Transfer Hydrogenation (CTH) of p-substituent acetophenone derivatives in the presence of KOH. The antimicrobial activities of the ligand and the complex have also been studied. The antimicrobial activities have been screened in vitro against Gram-positive (Staphylococcus aureus ATCC 6538, Bacillus cereus ATCC 7064, Listeria monocytogenes ATCC 15313, Micrococcus luteus La 2971) and Gram-negative (Escherichia coil ATCC 11230, Klebsiella pneumoniae UC57, Pseudomonas aeruginosa ATCC 27853, Proteus vulgaris ATCC 8427, Enterobacter aerogenes ATCC 13048) bacteria and yeast cultures (Candida albi cans ATCC 10231, Kluyveromyces fragills NRRL 2415, Rhodotorula rubra DSM 70403) using both the disk diffusion and dilution methods. (C) 2015 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [112T584]; Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey [F-279]
dc.description.sponsorshipWe are grateful to the Scientific and Technical Research Council of Turkey (TUBITAK) for financial support of this work, Grant Number 112T584. We also acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the SIDE IPDS II diffractometer (purchased under Grant No. F-279 of the University Research Fund).
dc.identifier.doi10.1016/j.poly.2014.12.040
dc.identifier.endpage175
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-84921657395
dc.identifier.scopusqualityQ2
dc.identifier.startpage170
dc.identifier.urihttps://doi.org/10.1016/j.poly.2014.12.040
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21165
dc.identifier.volume88
dc.identifier.wosWOS:000352748700021
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCyclophosphazene
dc.subjectRu(II) complex
dc.subjectCrystal structure
dc.subjectTransfer hydrogenation
dc.subjectAntimicrobial activity
dc.titleA new phosphazene derivative, spiro-N3P3[(O2C12H8)2(OC6H6N-3)2], and its Ru(II) complex: Syntheses, crystal structure, catalytic activity and antimicrobial activity studies
dc.typeArticle

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