Synthesis and characterization of a new dyestuff polymer soluble in alkaline aqueous media

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dc.authoridTemizkan Ozdamar, Kevser/0000-0001-7740-3252
dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorAydın, Aysel
dc.contributor.authorTemizkan, Kevser
dc.date.accessioned2025-01-27T20:54:18Z
dc.date.available2025-01-27T20:54:18Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractNovel dyestuff polymers were successfully obtained through oxidative polymerization technique. The synthesized Schiff base and its polymer were soluble in alkaline aqueous medium and they have various colors in different solutions. Also, it can be said that the synthesized compounds are suitable as coloring agent (dyestuff) for textile applications. Fluorescence properties of the compounds were determined in DMF with different concentrations (mg/L). Poly-tris(4-aminophenyl)methanol (P-TAPM) has quite high emission and excitation intensity values. Optical and electrochemical band gaps of the polymers were lower than those of the monomers indicating the more conjugated structure of the polymers. The oxidized states of the novel dyestuff compounds were examined by cyclic voltammetry (CV) technique. The solid state conductivity measurements showed that the synthesized polymers were semiconductors when exposed to the iodine vapour their conductivities could be increased. P-TAPM had the highest undoped conductivity. Thermal characterizations of the synthesized compounds were carried out by TG-DTA and DSC methods.
dc.identifier.doi10.1007/s10118-013-1361-1
dc.identifier.endpage1646
dc.identifier.issn0256-7679
dc.identifier.issn1439-6203
dc.identifier.issue12
dc.identifier.scopus2-s2.0-84887913729
dc.identifier.scopusqualityQ1
dc.identifier.startpage1632
dc.identifier.urihttps://doi.org/10.1007/s10118-013-1361-1
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26040
dc.identifier.volume31
dc.identifier.wosWOS:000326884900004
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofChinese Journal of Polymer Science
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectDyestuff polymers
dc.subjectThermal properties
dc.subjectFluorescence
dc.subjectOxidative polymerization
dc.titleSynthesis and characterization of a new dyestuff polymer soluble in alkaline aqueous media
dc.typeArticle

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