Metal-Ion-Containing Ionic Liquid Hydrogels and Their Application to Hydrogen Production

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dc.authoridŞahiner, Nurettin/0000-0003-0120-530X
dc.authoridAlpaslan, Duygu/0000-0002-6007-3397
dc.contributor.authorŞahiner, Nurettin
dc.contributor.authorAlpaslan, Duygu
dc.date.accessioned2025-01-27T20:46:09Z
dc.date.available2025-01-27T20:46:09Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA cationic hydrogel synthesized from (3-acrylamidopropyl) trimethyl ammonium chloride as poly[(3-acrylamidopropyl) trimethyl ammonium chloride] [p(APTMACl)] was put into contact with the chloride salts of metals such as CoCl2, NiCl2, and CuCl2 in ethanol. The metal-loaded p(APTMACl) hydrogels were used as catalyst systems in hydrogen generation from the hydrolysis of sodium borohydride (NaBH4) and ammonia borane. The activation energy values for the hydrolysis reaction were calculated for all of the catalyst systems and were found to be 53.43 and 26.74 kJ/mol for p(APTMACl)-[CoCl4](2-) and p(APTMACl)-[NiCl4](2-), respectively. These activation parameters were better than values reported in the literature for the ionic liquid metal complexes of smaller molecules used for the same purpose. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40183.
dc.description.sponsorshipScientific and Technological Research Council of Turkey [110T649]; Turkish Academy of Science through Turkish Academy of Science (TUBA) -GEBIP program
dc.description.sponsorshipThis work was supported by the Scientific and Technological Research Council of Turkey (contract grant number 110T649). One of the authors (N.S.) is grateful to the Turkish Academy of Science for its partial support through the 2008 Turkish Academy of Science (TUBA) -GEBIP program.
dc.identifier.doi10.1002/app.40183
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue9
dc.identifier.scopus2-s2.0-84895063065
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1002/app.40183
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24824
dc.identifier.volume131
dc.identifier.wosWOS:000334599600004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofJournal of Applied Polymer Science
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectcatalysts
dc.subjectcomposites
dc.subjectgels
dc.subjectionic liquids
dc.subjectpolyelectrolytes
dc.titleMetal-Ion-Containing Ionic Liquid Hydrogels and Their Application to Hydrogen Production
dc.typeArticle

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