Metal-Ion-Containing Ionic Liquid Hydrogels and Their Application to Hydrogen Production
dc.authorid | Şahiner, Nurettin/0000-0003-0120-530X | |
dc.authorid | Alpaslan, Duygu/0000-0002-6007-3397 | |
dc.contributor.author | Şahiner, Nurettin | |
dc.contributor.author | Alpaslan, Duygu | |
dc.date.accessioned | 2025-01-27T20:46:09Z | |
dc.date.available | 2025-01-27T20:46:09Z | |
dc.date.issued | 2014 | |
dc.department | Çanakkale Onsekiz Mart Üniversitesi | |
dc.description.abstract | A cationic hydrogel synthesized from (3-acrylamidopropyl) trimethyl ammonium chloride as poly[(3-acrylamidopropyl) trimethyl ammonium chloride] [p(APTMACl)] was put into contact with the chloride salts of metals such as CoCl2, NiCl2, and CuCl2 in ethanol. The metal-loaded p(APTMACl) hydrogels were used as catalyst systems in hydrogen generation from the hydrolysis of sodium borohydride (NaBH4) and ammonia borane. The activation energy values for the hydrolysis reaction were calculated for all of the catalyst systems and were found to be 53.43 and 26.74 kJ/mol for p(APTMACl)-[CoCl4](2-) and p(APTMACl)-[NiCl4](2-), respectively. These activation parameters were better than values reported in the literature for the ionic liquid metal complexes of smaller molecules used for the same purpose. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40183. | |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey [110T649]; Turkish Academy of Science through Turkish Academy of Science (TUBA) -GEBIP program | |
dc.description.sponsorship | This work was supported by the Scientific and Technological Research Council of Turkey (contract grant number 110T649). One of the authors (N.S.) is grateful to the Turkish Academy of Science for its partial support through the 2008 Turkish Academy of Science (TUBA) -GEBIP program. | |
dc.identifier.doi | 10.1002/app.40183 | |
dc.identifier.issn | 0021-8995 | |
dc.identifier.issn | 1097-4628 | |
dc.identifier.issue | 9 | |
dc.identifier.scopus | 2-s2.0-84895063065 | |
dc.identifier.scopusquality | Q2 | |
dc.identifier.uri | https://doi.org/10.1002/app.40183 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12428/24824 | |
dc.identifier.volume | 131 | |
dc.identifier.wos | WOS:000334599600004 | |
dc.identifier.wosquality | Q2 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | |
dc.publisher | Wiley | |
dc.relation.ispartof | Journal of Applied Polymer Science | |
dc.relation.publicationcategory | info:eu-repo/semantics/openAccess | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.snmz | KA_WoS_20250125 | |
dc.subject | catalysts | |
dc.subject | composites | |
dc.subject | gels | |
dc.subject | ionic liquids | |
dc.subject | polyelectrolytes | |
dc.title | Metal-Ion-Containing Ionic Liquid Hydrogels and Their Application to Hydrogen Production | |
dc.type | Article |