A new approach for synthesis of electroactive phenol based polymer: 4-(2,5-Di(thiophen-2-yl)-1H-pyrrol-1-yl)phenol and its oxidative polymer

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorAydın, Aysel
dc.date.accessioned2025-01-27T20:27:41Z
dc.date.available2025-01-27T20:27:41Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, the 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)phenol (4-DTPP) was synthesized by the reaction of 1,4-di(2-thienyl)-1,4-butanedione and 4-aminophenol. This monomer was electrochemically polymerized in the presence of LiClO4 as the supporting electrolyte in acetonitrile (AN). The copolymerization were achieved in the presence of thiophene (Th) with 3,4-ethylenedioxythiophene (EDOT) in 0.1 M LiClO4/AN electrolyte-solvent couple. The polymer of 4-(2.5-di(thiophen-2-yl)-1H-pyrrol-1-yl)phenol was synthesized by oxidative polycondensation reaction in an aqueous alkaline medium using NaOCl (30%) as oxidant. The structures of compounds were confirmed by FT-IR, UV-vis, and H-1-NMR techniques. The characterizations of compounds were made by TG-DTA, DSC, gel permeation chromatography (GPC) and solubility tests. Electrical conductivities of the synthesized monomer and polymer were measured by four-point probe technique using a Keithley 2400 electrometer. Fluorescence measurements were carried out in various solvents. (C) 2011 Elsevier B.V. All rights reserved.
dc.description.sponsorshipGovernment Planning Organization [GP02010K120710]
dc.description.sponsorshipWe would like to thank Government Planning Organization for the financial support (project no: GP02010K120710).
dc.identifier.doi10.1016/j.porgcoat.2011.11.008
dc.identifier.endpage249
dc.identifier.issn0300-9440
dc.identifier.issue2-3
dc.identifier.scopus2-s2.0-84655176712
dc.identifier.scopusqualityQ1
dc.identifier.startpage239
dc.identifier.urihttps://doi.org/10.1016/j.porgcoat.2011.11.008
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22755
dc.identifier.volume73
dc.identifier.wosWOS:000300136000017
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofProgress in Organic Coatings
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectElectropolymerization
dc.subjectPolyphenol
dc.subjectOxidative polymerization
dc.subjectCyclic voltammetry
dc.titleA new approach for synthesis of electroactive phenol based polymer: 4-(2,5-Di(thiophen-2-yl)-1H-pyrrol-1-yl)phenol and its oxidative polymer
dc.typeReview Article

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