Determination of the thermodynamic properties of poly [2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] at infinite dilution by inverse gas chromatography

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorDemirelli, Kadir
dc.date.accessioned2025-01-27T20:11:40Z
dc.date.available2025-01-27T20:11:40Z
dc.date.issued2001
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractSome thermodynamic quantities were obtained for the interactions of poly [2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] Poly (PCHEMA-co-MA) with alcohols, ketones, acetates, aromatics and n-alkanes by inverse gas chromatography in the temperature range of 150-180 degreesC. The specific retention volumes, Vg degrees. weight fraction activity coefficients of solute probes at infinite dilution, Omega (infinity)(1) and Flory-Huggins thermodynamic interaction parameters, chi (infinity)(12) between polymers and solvents were determined. The partial molar free energy, DeltaG(1)(infinity), the partial molar heat of mixing, DeltaH(1)(infinity). at infinite dilution and the solubility parameters of the polymer, delta (2), were calculated. The copolymer was characterized by H-1-NMR, FT-IR and DSC analyses.
dc.identifier.endpage18
dc.identifier.issn1010-7614
dc.identifier.issue1
dc.identifier.scopus2-s2.0-0035582784
dc.identifier.scopusqualityQ3
dc.identifier.startpage11
dc.identifier.urihttps://hdl.handle.net/20.500.12428/20666
dc.identifier.volume25
dc.identifier.wosWOS:000167268000002
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherScientific Technical Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectpoly [2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid]
dc.subjectinverse gas chromatography
dc.subjectpolymer-solvent interactions
dc.titleDetermination of the thermodynamic properties of poly [2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] at infinite dilution by inverse gas chromatography
dc.typeArticle

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