New polyfluorinated porphyrazine complexes: synthesis, characterization, aggregation, and solubility

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dc.contributor.authorGonca, Ergun
dc.date.accessioned2025-01-27T21:05:25Z
dc.date.available2025-01-27T21:05:25Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractBy cyclotetramerization of 2,3-bis(2,3,5,6-tetrafluoro-4-methylbenzylthio) maleonitrile in the presence of magnesium butoxide, magnesium porphyrazinate (MgPz) carrying eight (2,3,5,6-tetrafluoro-4-methylbenzylthio) functional units on the periphery positions has been synthesized. Conversion of MgPz into the metal-free derivative was achieved upon addition of a strong acid such as trifluoroacetic acid. Further reaction of this product with different metal(II) acetates led to metallo porphyrazines (MPz). The monomeric bisaxial complex FePz(py)(2) as well as the bridged complex [FePz(pyz)]n were formed as stable complexes by reacting FePzCl with pyridine or pyrazine, respectively. These complexes were characterized by elemental analysis, together with FT-IR, H-1 NMR, C-13 NMR, F-19 NMR, UV-vis, and mass spectral data. [GRAPHICS] .
dc.description.sponsorshipScientific Research Fund of Canakkale Onsekiz Mart University [FBA-2014-238]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of Canakkale Onsekiz Mart University [project number FBA-2014-238].
dc.identifier.doi10.1080/00958972.2017.1350267
dc.identifier.endpage2358
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue13
dc.identifier.scopus2-s2.0-85022222425
dc.identifier.scopusqualityQ3
dc.identifier.startpage2344
dc.identifier.urihttps://doi.org/10.1080/00958972.2017.1350267
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27629
dc.identifier.volume70
dc.identifier.wosWOS:000406484500011
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subject4-Methyl-2,3,5,6-tetrafluorobenzyl bromide
dc.subjectpyrazine
dc.subjectF-19 NMR Spectroscopy
dc.subjectoligomeric complex
dc.subjectaggregation
dc.titleNew polyfluorinated porphyrazine complexes: synthesis, characterization, aggregation, and solubility
dc.typeArticle

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