Bis{2,6-bis[1-(4-fluorophenylimino)ethyl]pyridine}-1?3N,N?,N;3?3N,N?,N-di-?-chlorido-1:2?2Cl:Cl;-2:3?2Cl:Cl-trichlorido-1?Cl,2?Cl,3?Cl-2-copper(I)-1,3-dicopper(II)

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dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDincer, Muharrem
dc.contributor.authorDayan, Osman
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2025-01-27T20:56:01Z
dc.date.available2025-01-27T20:56:01Z
dc.date.issued2008
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe title complex, [Cu3Cl5(C21H17N3F2)(2)], is the first reported copper trimer including both Cu-I and Cu-II ions. The two Cu-II ions are five-coordinate in a significantly distorted square-pyramidal arrangement, with the bridging Cl atom located in the apical position, and the pyridine (py) N atom, the two imine N atoms and the other Cl atom located in the basal plane. The Cu-I ion is in a trigonal planar configuration surrounded by three Cl atoms. The structure is stabilized by intra- and intermolecular C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi(py) hydrogen bonds.
dc.identifier.doi10.1107/S0108270108012237
dc.identifier.endpageM227
dc.identifier.issn2053-2296
dc.identifier.pmid18535329
dc.identifier.scopus2-s2.0-44949260928
dc.identifier.scopusqualityN/A
dc.identifier.startpageM224
dc.identifier.urihttps://doi.org/10.1107/S0108270108012237
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26279
dc.identifier.volume64
dc.identifier.wosWOS:000256468200003
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherInt Union Crystallography
dc.relation.ispartofActa Crystallographica Section C-Structural Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectRuthenium(Ii) Complexes
dc.subjectEthylene Polymerization
dc.subjectCatalytic-Activity
dc.subjectLigands
dc.subjectCrystal
dc.titleBis{2,6-bis[1-(4-fluorophenylimino)ethyl]pyridine}-1?3N,N?,N;3?3N,N?,N-di-?-chlorido-1:2?2Cl:Cl;-2:3?2Cl:Cl-trichlorido-1?Cl,2?Cl,3?Cl-2-copper(I)-1,3-dicopper(II)
dc.typeArticle

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