A novel shape-controlled synthesis of bifunctional organic polymeric nanoparticles

dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridTemizkan Özdamar, Kevser / 0000-0001-7740-3252
dc.authoridDoğan, Fatih / 0000-0002-3088-886X
dc.contributor.authorDoğan, Fatih
dc.contributor.authorTemizkan, Kevser
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:57:46Z
dc.date.available2025-01-27T20:57:46Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA novel shape-controlled bifunctional organic nanoparticle was reported using the facile synthesis of self-stabilized monohydroxy amino naphthol nanoparticles. For this purpose, bifunctional monomer was polymerized by NaOCl as oxidant in aqueous alkaline medium at 70 degrees C. These poly-nanoparticles with molecular weight ca. 5000 Da was obtained by template-free oxidative polymerization (OP) process. The structure of polymer was confirmed by NMR, FT-IR, UV-Vis and X-RD measurements. The chemical and physical properties of polymer were determined size exclusion chromatography (SEC), thermogravimetry (TG), differential scanning calorimetry (DSC), cyclic voltammetry (CV), photoluminescence (PL), dynamic light scattering (DLS), scanning electron microscope (SEM), transmission electron microscope (TEM) and conductivity techniques. The SEM analysis of polymer indicated to be had a nanoparticle structure. The reversible redox behavior of the polymer was attributed to its electroactive nature. In addition, the kinetic parameters related to the solid state decomposition of the poly-nanoparticles were calculated by non-isothermal methods based on multiple heating rates. (C) 2015 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUB_ITAK) [211T119]
dc.description.sponsorshipThe authors thanks to the Scientific and Technological Research Council of Turkey (TUB_ITAK) for support with the project (Project No: 211T119).
dc.identifier.doi10.1016/j.polymer.2015.06.007
dc.identifier.endpage67
dc.identifier.issn0032-3861
dc.identifier.issn1873-2291
dc.identifier.scopus2-s2.0-84934995343
dc.identifier.scopusqualityQ1
dc.identifier.startpage59
dc.identifier.urihttps://doi.org/10.1016/j.polymer.2015.06.007
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26487
dc.identifier.volume70
dc.identifier.wosWOS:000358005000009
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofPolymer
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPoly(amino naphthol)
dc.subjectOxidative polymerization
dc.subjectSemi-conductivity
dc.subjectThermal stability
dc.subjectActivation energy
dc.subjectPoly nanoparticles
dc.titleA novel shape-controlled synthesis of bifunctional organic polymeric nanoparticles
dc.typeArticle

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