Synthesis of some ruthenium(II)-Schiff base complexes bearing sulfonamide fragment: New catalysts for transfer hydrogenation of ketones

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dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.authoriddayan, serkan/0000-0003-4171-7297
dc.contributor.authorDayan, Serkan
dc.contributor.authorOzpozan, Nilgun Kalaycioglu
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDayan, Osman
dc.date.accessioned2025-01-27T20:54:27Z
dc.date.available2025-01-27T20:54:27Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractFour new ruthenium(II) complexes [RuCl(1-4)(p-cymene)] (1-4 = N-(3-(2-hydroxybenzylideneamino)phenyl) benzenesulfonamides) were synthesized from [RuCl2(p-cymene)](2) with Schiff base ligands containing aromatic sulfonamide fragment, and characterized by spectroscopic techniques including H-1 and C-13 NMR, FT-IR, single crystal X-ray diffraction and by elemental analysis. Additionally, all the synthesized Ru(II) complexes were tested as catalysts for the reactions in the transfer hydrogenation (TH) of acetophenone derivatives. The results showed that these facile synthesized Ru(II) complexes are efficient catalysts in this reaction (turnover frequency: 1260 h(-1) for 6). (C) 2014 Elsevier B. V. All rights reserved.
dc.description.sponsorshipErciyes University (ERUBAP) [FBA-11-3547]; University Research Fund [F-279]
dc.description.sponsorshipWe would like to thank the financial support granted by Erciyes University (ERUBAP), (FBA-11-3547, ID: 3547). We acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the STOE IPDS II diffractometer (purchased under grant No. F-279 of the University Research Fund).
dc.identifier.doi10.1016/j.jorganchem.2014.08.002
dc.identifier.endpage28
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-84906536198
dc.identifier.scopusqualityQ2
dc.identifier.startpage21
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2014.08.002
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26080
dc.identifier.volume770
dc.identifier.wosWOS:000342569500004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectTransfer hydrogenation
dc.subjectSulfonamide
dc.subjectRuthenium
dc.subjectBidentate ligand
dc.titleSynthesis of some ruthenium(II)-Schiff base complexes bearing sulfonamide fragment: New catalysts for transfer hydrogenation of ketones
dc.typeArticle

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