Synthesis, structural characterization, and anion interactions of new triazole-linked urea derivative fully substituted cyclotriphosphazene compounds

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dc.authoridOzay, Hava/0000-0002-4184-7801
dc.contributor.authorÖzay, Özgür
dc.contributor.authorYildirim, Mehmet
dc.contributor.authorOzay, Hava
dc.date.accessioned2025-01-27T20:25:11Z
dc.date.available2025-01-27T20:25:11Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThree novel fully substituted urea derivative cyclotriphosphazene compounds 5-7 were synthesized by alkyne-azide 1,3-dipolar cycloaddition reaction of propargyl substituted ureas 2-4 with hexaazide substituted cyclotriphosphazene 1 in the presence of Cu(I) catalyst. All compounds were characterized with spectroscopic techniques such as FT-IR, H-1, C-13, and P-31 nuclear magnetic resonance and mass spectroscopy. Also, the usefulness of compounds 5-7 as anion carriers was investigated by H-1 NMR spectroscopy. For this purpose, H-1 NMR spectra of compounds 5-7 were recorded in the presence of tetrabutylammonium fluoride in DMSO-d(6). It was determined, that the urea protons in the compounds interact with fluoride.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112T278]
dc.description.sponsorshipThe authors gratefully acknowledge the Scientific and Technological Research Council of Turkey (TUBITAK, Project No: 112T278) for financial support.
dc.identifier.doi10.1080/10426507.2016.1237950
dc.identifier.endpage315
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue3
dc.identifier.scopus2-s2.0-85007377531
dc.identifier.scopusqualityQ3
dc.identifier.startpage307
dc.identifier.urihttps://doi.org/10.1080/10426507.2016.1237950
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22453
dc.identifier.volume192
dc.identifier.wosWOS:000395128800010
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofPhosphorus Sulfur and Silicon and The Related Elements
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectAzide-alkyne cycloaddition
dc.subjectcyclotriphosphazene
dc.subjecturea
dc.subjectclick reaction
dc.subjecthexapodal compound
dc.titleSynthesis, structural characterization, and anion interactions of new triazole-linked urea derivative fully substituted cyclotriphosphazene compounds
dc.typeArticle

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