A new ITO-compatible side chain-functionalized multielectrochromic polymer for use in adaptive camouflage-like electrochromic devices

dc.authoridKoyuncu, Sermet/0000-0001-8352-8326
dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorKoyuncu, Fatma Baycan
dc.date.accessioned2025-01-27T20:22:35Z
dc.date.available2025-01-27T20:22:35Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, a new electroactive monomer, 3-(244-(2,5-di-2-thienyl-1H-pyrrol-1-yl)phenyl]ethyl-thio)propanoic acid (SNSPA), was synthesized and then deposited onto the ITO/glass surface by an electrochemical process. When positive potentials were applied on the polymer film of SNSPA, the film at the neutral state turned from orange to green (0.6 V) and then to blue (1.1 V) because of the presence of polaronic and bipolaronic species on the SNS main chain of the polymer. At the last stage, a complementary electrochromic device was constructed by using poly(SNSPA) as the anode layer and PEDOT:PSS as the cathode layer. A fast response time (about 0.5 s) and a high stability of about 98% were obtained at the end of 1000 cycles. The capability of the proposed polymer to undergo reversible color change among brown, green, and blue is a significant property for use as an adaptive camouflage material for all conditions of sand, forest, and sea for military applications.
dc.description.sponsorshipCanakkale Onsekiz Mart University [2016/1083]
dc.description.sponsorshipThe authors would like to thank Canakkale Onsekiz Mart University for financial support (Project Number: 2016/1083).
dc.identifier.doi10.1016/j.reactfunctpolym.2018.07.024
dc.identifier.endpage180
dc.identifier.issn1381-5148
dc.identifier.issn1873-166X
dc.identifier.scopus2-s2.0-85051103282
dc.identifier.scopusqualityQ1
dc.identifier.startpage174
dc.identifier.urihttps://doi.org/10.1016/j.reactfunctpolym.2018.07.024
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21957
dc.identifier.volume131
dc.identifier.wosWOS:000448225200020
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofReactive & Functional Polymers
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectElectrochromic polymers
dc.subject2,5-di-(2-thienyl)-1H-pyrrole
dc.subjectAdaptive camouflage
dc.titleA new ITO-compatible side chain-functionalized multielectrochromic polymer for use in adaptive camouflage-like electrochromic devices
dc.typeArticle

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