Photoinduced Step-Growth Polymerization of N-Ethylcarbazole

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dc.authoridYilmaz, Gorkem/0000-0002-8638-4548
dc.authoridKoyuncu, Sermet/0000-0001-8352-8326
dc.contributor.authorSari, Erdem
dc.contributor.authorYilmaz, Gorkem
dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2025-01-27T21:03:37Z
dc.date.available2025-01-27T21:03:37Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA novel method for photochemical step growth synthesis of poly(N-ethylcarbazole) (PEC) via consecutive diphenyl iodonium hexafluorophospate (Ph2I+PF6-) mediated electron transfer and coupling reactions is reported. The photoinduced electron transfer reaction of the excited N-ethylcarbazole (EC) in the presence of Ph2I+PF6- as the oxidizing salt proceeded efficiently giving EC radical cations (EC+center dot). Subsequently, the protons released concomitantly with coupling of two EC radical cations. The successive reactions involving excitation, electron transfer, proton release, and coupling lead to the formation of PEC. The electrochemical properties and surface morphology of the thin films of the formed polymers before and after dedoping were investigated by cyclic voltammetry, differential pulse voltammetry, and atomic force microscopy techniques, respectively.
dc.description.sponsorshipIstanbul Technical University
dc.description.sponsorshipThe authors thank Istanbul Technical University for financial support.
dc.identifier.doi10.1021/jacs.8b08668
dc.identifier.endpage12731
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.issue40
dc.identifier.pmid30257091
dc.identifier.scopus2-s2.0-85054360155
dc.identifier.scopusqualityQ1
dc.identifier.startpage12728
dc.identifier.urihttps://doi.org/10.1021/jacs.8b08668
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27373
dc.identifier.volume140
dc.identifier.wosWOS:000447354800016
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of The American Chemical Society
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectTransfer Radical Polymerization
dc.subjectCationic-Polymerization
dc.subjectSolar-Cells
dc.subjectConjugated Polymers
dc.subjectLight
dc.subjectPhotocatalyst
dc.subjectComposite
dc.subjectChemistry
dc.subjectMonomers
dc.subjectSalts
dc.titlePhotoinduced Step-Growth Polymerization of N-Ethylcarbazole
dc.typeArticle

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