A Binary Solvent Dispersive Liquid-Liquid Microextraction Method for the Determination of Four Endocrine Disruptor Compounds by Gas Chromatography with Flame Ionization Detector

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dc.authoridCHORMEY, DOTSE SELALI/0000-0002-7412-7800
dc.authoridYAMAN, Burcu/0000-0002-0836-4891
dc.authoridDilgin, Yusuf/0000-0002-2980-6871
dc.authoridZaman, Buse Tugba/0000-0003-0542-1050
dc.contributor.authorYaman, Burcu
dc.contributor.authorZaman, Buse Tugba
dc.contributor.authorChormey, Dotse Selali
dc.contributor.authorBakirdere, Sezgin
dc.contributor.authorDilgin, Yusuf
dc.date.accessioned2025-01-27T20:59:40Z
dc.date.available2025-01-27T20:59:40Z
dc.date.issued2022
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe present study reports a precise and accurate binary dispersive liquid-liquid microextraction method for the enrichment of selected endocrine disruptor compounds for determination by gas chromatography flame ionization detector. Optimal variables of influential extraction parameters (binary solvent volume, disperser solvent volume, and vortex period) were determined with a design experiment. The main effects of these parameters were examined using analysis of variance (ANOVA), and the optimum parameters of the model were obtained from the model predictor. The analytes recorded detection limits varying between 0.43 and 2.7 ng/mL under the optimum experimental conditions. All the analytes exhibited good linearity and high precision (%RSD<10%) for six replicate measurements of the lowest calibration concentrations. The enhancement in calibration sensitivity for the analytes in GC-FID was found in the range of 41.9-64.5 times for each analyte by applying the developed method. The accuracy and feasibility of the method was assessed using water samples from a well and a hospital sewer, and the percent recovery results calculated using matrix matching calibration were in the range of 90-113%. These results demonstrated that the analytes can be accurately quantified in real aqueous matrices using the developed method.
dc.identifier.doi10.1007/s11270-022-05632-7
dc.identifier.issn0049-6979
dc.identifier.issn1573-2932
dc.identifier.issue5
dc.identifier.scopus2-s2.0-85129736779
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1007/s11270-022-05632-7
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26780
dc.identifier.volume233
dc.identifier.wosWOS:000791922400001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Int Publ Ag
dc.relation.ispartofWater Air and Soil Pollution
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectEndocrine disruptor compounds
dc.subjectPesticides
dc.subjectMultivariate optimization
dc.subjectBinary solvent microextraction
dc.subjectDLLME
dc.subjectGC-FID
dc.titleA Binary Solvent Dispersive Liquid-Liquid Microextraction Method for the Determination of Four Endocrine Disruptor Compounds by Gas Chromatography with Flame Ionization Detector
dc.typeArticle

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