Biological Activity and Optical Sensor Properties of Green Synthesis Polymer

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dc.authoridSENOL BAHCECI, Dilek/0000-0001-7854-0419
dc.contributor.authorBahceci, Dilek Senol
dc.contributor.authorDemir, Neslihan
dc.contributor.authorKocaeren, Aysel Aydin
dc.date.accessioned2025-01-27T20:27:26Z
dc.date.available2025-01-27T20:27:26Z
dc.date.issued2022
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, 4-amino-3-hydroxy-1-naphthalene sulfonic acid (Monomer) was converted to its enzyme-catalyzed oxidative polymerization (Poly-enz) in dioxane solvent by horseradish peroxidase enzyme (HRP) in the presence of hydrogen peroxide as oxidant. For the analysis of the monomer and its synthesized Poly-enz, H-1-NMR, C-13-NMR, FT-IR, TGA, and SEM measurements were determined. In addition, the optical ion sensor properties of Poly-enz against metals such as Ag+, Cd2+, Co2+, Hg2+, Ni2+, Pb2+, Zn2+, Cu2+ were examined with UV-Vis spectrophotometer. It was observed that Cu metal showed sensory properties. DNA cleavage and DNA binding activities of monomer and Poly-enz were done using by agarose gel electrophoresis and UV-Vis methods, respectively. It was seen that the Poly-enz interacted with DNA electrostatically. This enzymatic polymer was found to cleave pBR322 plasmid DNA both hydrolytically and oxidatively as well. The antioxidant activities of the compounds were examined by three different methods (DPPH, ABTS, FRAP) and it was found that the Poly-enz showed high antioxidant activity compared to its monomer. Antimicrobial activities were studied against various bacterial and yeast cultures by the minimum inhibition concentration (MIC) method. It was observed that the antimicrobial activities of the enzymatic polymer in different microorganisms increased depending on the concentration.
dc.description.sponsorshipCanakkale Onsekiz Mart University Scientific Research Coordination Unit [FBA-2021-3504]
dc.description.sponsorshipThe authors thank the support of the Canakkale Onsekiz Mart University Scientific Research Coordination Unit (Project number: FBA-2021-3504).
dc.identifier.doi10.1002/slct.202202096
dc.identifier.issn2365-6549
dc.identifier.issue34
dc.identifier.scopus2-s2.0-85137988677
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1002/slct.202202096
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22689
dc.identifier.volume7
dc.identifier.wosWOS:000852060900001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChemistryselect
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCharacterization
dc.subjectDNA binding
dc.subjectDNA cleavage
dc.subjectEnzymatic polymerization
dc.subjectOptical sensor
dc.titleBiological Activity and Optical Sensor Properties of Green Synthesis Polymer
dc.typeArticle

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