One-pot stepwise reductive amination reaction by N-coordinate sulfonamido-functionalized Ru(II) complexes in water

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dc.authoridKAYACI, Nilgun/0000-0002-7988-8668
dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.authoriddayan, serkan/0000-0003-4171-7297
dc.contributor.authorKayaci, Nilgun
dc.contributor.authorDayan, Serkan
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDayan, Osman
dc.contributor.authorOzpozan, Nilgun Kalaycioglu
dc.date.accessioned2025-01-27T21:03:37Z
dc.date.available2025-01-27T21:03:37Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractNew complexes of formula [RuCl(p-cymene)(L)] (7-12) were prepared with [RuCl2(p-cymene)](2) and pre-synthesized N-arenesulfonly-o-phenylenediamines (1-6) and characterized using H-1 NMR, C-13 NMR, Fourier transform infrared and UV-visible spectroscopic techniques, and single-crystal X-ray diffraction analysis was performed for one complex (8). Complexes 7-12 were investigated in the reduced imine synthesis reaction (in the presence of HCOONa/HCOOH). The best turnover frequency values were found to be 100 h(-1) for 1 and 99 h(-1) for 6 in the transfer hydrogenative reductive amination reaction of 4-methoxyaniline and 3,4,5-trimethoxybenzaldehyde. The most important feature of this reaction is that it is an environmental friendly procedure because of being conducted in an aqueous environment. That no organic solvent is used allows one to say that this reaction represents green chemistry.
dc.description.sponsorshipErciyes University (ERUBAP) [FDK-2015-6143 ID: 6143]; TUBITAK (BIDEB)
dc.description.sponsorshipErciyes University (ERUBAP), Grant/Award Number: FDK-2015-6143 ID: 6143; TUBITAK (BIDEB)
dc.identifier.doi10.1002/aoc.4558
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue12
dc.identifier.scopus2-s2.0-85054569796
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1002/aoc.4558
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27371
dc.identifier.volume32
dc.identifier.wosWOS:000451408700017
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectcatalytic
dc.subjectreductive amination reaction
dc.subjectruthenium
dc.subjectsulfonamido
dc.titleOne-pot stepwise reductive amination reaction by N-coordinate sulfonamido-functionalized Ru(II) complexes in water
dc.typeArticle

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