Hydrogel assisted nickel nanoparticle synthesis and their use in hydrogen production from sodium boron hydride

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dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.authoridÖzay, Özgür / 0000-0001-6589-9844
dc.contributor.authorÖzay, Özgür
dc.contributor.authorAktaş, Nahit
dc.contributor.authorİnger, Erk
dc.contributor.authorŞahiner, Nurettin
dc.date.accessioned2025-01-27T20:56:01Z
dc.date.available2025-01-27T20:56:01Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, hydrogels were synthesized from 2-acrylamido-2-methyl-1-propansulfonic acid (AMPS) via a photo polymerization technique. Approximately 100 nm Ni metal nanoparticles were generated in situ inside these p(AMPS) hydrogel networks and used as a catalyst in hydrogen production by hydrolysis of sodium boron hydride in a basic medium. The effects of several parameters on the hydrolysis reaction such as the amount of catalyst, the initial concentration of NaBH4, and the temperature were investigated. The activation energy, activation enthalpy and activation of entropy for the reaction were calculated as 42.28 kJ mol(-1), 39.59 kJ mol(-1) and -171.67 J mol(-1) K-1, respectively. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
dc.description.sponsorshipNational BOREN Institute of Turkey; Turkish Academy of Science
dc.description.sponsorshipThis work is supported by National BOREN Institute of Turkey. N. Sahiner also greatly acknowledges to the Turkish Academy of Science for the partial support under 2008 TUBA-GEBIP program.
dc.identifier.doi10.1016/j.ijhydene.2010.11.045
dc.identifier.endpage2006
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue3
dc.identifier.scopus2-s2.0-79551618335
dc.identifier.scopusqualityQ1
dc.identifier.startpage1998
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2010.11.045
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26278
dc.identifier.volume36
dc.identifier.wosWOS:000288825800013
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectHydrogen
dc.subjectHydrogel-nanoreactor
dc.subjectCatalysis
dc.subjectNanocluster
dc.subjectNaBH4 Hydrolysis
dc.subjectNi nanoparticles
dc.titleHydrogel assisted nickel nanoparticle synthesis and their use in hydrogen production from sodium boron hydride
dc.typeArticle

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