Azomethine-based phenol polymer: Synthesis, characterization and thermal study

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.contributor.authorBilici, Ali
dc.date.accessioned2025-01-27T20:45:26Z
dc.date.available2025-01-27T20:45:26Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractAzomethine-based phenol polymer, poly-2-{[(6-aminopyridin-2-yl)imino]methyl}-phenol (PAPIMP), was synthesized through the combination of condensation reaction and oxidative polymerization. Polymer isolated from aqueous solution was characterized by UV-vis, FT-IR, NMR and TG, SEC analysis. According to the SEC chromatograms, the number-average molecular weight (M(n)), weight-average molecular weight (M(w)) and polydispersity index (PDI) values of PAPIMP were determined to be 33,550, 78,900 g mol(-1) and 2.352, respectively. Also, optical band gaps (E(g)) of APIMP and PAPIMP calculated from cyclic voltammetry (CV) measurements. Also, electrical conductivities of each component measured with four-point probe technique. TG analysis showed that PAPIMP was stable up to 300 degrees C. The thermal decomposition kinetics of PAPIMP was investigated by means of thermogravimetric analysis in dynamic nitrogen atmosphere at four different heating rates: 5, 10, 15 and 20 degrees C min(-1) The apparent activation energies for thermal decomposition of PAPIMP were obtained by Tang, Flynn-Wall-Ozawa (FWO), Kissenger-Akahira-Sunose (KAS) and Coats-Redfern methods (CR) were 96.97, 105.33, 97.28 and 88.60 kJ mol(-1), respectively; the mechanism function and pre-exponential factor were determined by master plots method. The most likely decomposition process was a D(n) Deceleration type in terms of the Coats-Redfern and master plots results. (C) 2010 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.synthmet.2010.11.001
dc.identifier.endpage86
dc.identifier.issn0379-6779
dc.identifier.issue1-2
dc.identifier.scopus2-s2.0-78650862848
dc.identifier.scopusqualityQ1
dc.identifier.startpage79
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2010.11.001
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24567
dc.identifier.volume161
dc.identifier.wosWOS:000287383800012
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectOxidative polymerization
dc.subjectSchiff base polymer
dc.subjectKinetic parameter
dc.titleAzomethine-based phenol polymer: Synthesis, characterization and thermal study
dc.typeArticle

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