Synthesis and characterization of an acrylate polymer containing chlorine-1,3-dioxalane groups in side chains

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridDoğan, Fatih / 0000-0002-3088-886X
dc.authoridDoğan, Fatih / 0000-0001-5844-8893
dc.contributor.authorİlter, Zülfiye
dc.contributor.authorAlhanlı, Ferhat
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T21:01:51Z
dc.date.available2025-01-27T21:01:51Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPoly[2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methyl acrylate, poly(CPhDMA), was synthesized with radical polymerization process using 2,2'-azobisisobutyronitrile as radical initiator in 1,4-dioxane at 60A degrees C. The structure of poly(CPhDMA) was confirmed by means of UV-Vis, FT-IR, H-1-NMR, and C-13-NMR spectral techniques. The molecular weight distribution values of the polymer were determined with gel permeation chromatography (GPC). The number-average molecular weight (M (n)), weight-average molecular weight (M (w)) and polydispersity index (PDI) values of poly(CPhDMA) were determined to be 10300, 21600 and 2.097, respectively. The thermal degradation kinetics of the polymer was investigated by using TG/DTG-DTA and DSC analyses at different heating rates in dynamic nitrogen atmosphere. The apparent activation energy values obtained by Flynn-Wall-Ozawa and Friedman methods were found to be 91.68 and 85.23 kJ mol(-1), respectively, for thermal decomposition of poly(CPhDMA). Also, the thermal degradation activation energy value of poly(CPhDMA) was calculated by using the Kissinger method based on the DTG, DTA and DSC data. Then the mechanism function of it was determined by master plots method. Finally, electrical and optical properties of poly(CPhDMA) were determined by four-point probe and UV-Vis techniques, respectively.
dc.identifier.doi10.1007/s10118-012-1155-x
dc.identifier.endpage651
dc.identifier.issn0256-7679
dc.identifier.issn1439-6203
dc.identifier.issue5
dc.identifier.scopus2-s2.0-84869509867
dc.identifier.scopusqualityQ1
dc.identifier.startpage642
dc.identifier.urihttps://doi.org/10.1007/s10118-012-1155-x
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27211
dc.identifier.volume30
dc.identifier.wosWOS:000307246500004
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofChinese Journal of Polymer Science
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectSynthesis of acrylate polymer
dc.subjectThermal degradation
dc.subjectKinetic parameters
dc.titleSynthesis and characterization of an acrylate polymer containing chlorine-1,3-dioxalane groups in side chains
dc.typeArticle

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