Asymmetrically tetra-substituted phthalocyanine derivatives: synthesis, photophysical and photochemical properties

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dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.contributor.authorDilber, Gulsev
dc.contributor.authorNas, Asiye
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorDurmus, Mahmut
dc.date.accessioned2025-01-27T20:50:34Z
dc.date.available2025-01-27T20:50:34Z
dc.date.issued2022
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe syntheses of highly soluble asymmetrically substituted metal free and zinc phthalocyanine derivatives bearing three 4-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenoxy) and one 4-(2-(benzo[d]thiazol-2-yl)phenoxy) groups or bearing one 4-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenoxy) and three 4-(2-(benzo[d]thiazol-2-yl)phenoxy) groups were reported for the first time in this study. The successful synthesis of phthalocyanines was achieved through the common statistical condensation method utilizing two different phthalonitriles named as 4-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenoxy)phthalonitrile and 4-(2-(benzo[d]thiazol-2-yl)phenoxy)phthalonitrile. The asymmetrical phthalocyanines were characterized by spectroscopic methods. Moreover, the aggregation behavior, photophysical and photochemical properties of the substituted A(3)B type asymmetrical metal free and Zn (II) phthalocyanines were investigated in DMF. The asymmetrical Zn (II) phthalocyanine complexes produced highly singlet oxygen and appropriate fluorescence behavior in DMF suggesting that they can be suitable candidates as Type II photosensitizers in photodynamic therapy (PDT) applications.
dc.description.sponsorshipResearch Fund of Karadeniz Technical University [FBA-2019-7741]
dc.description.sponsorshipThis study was supported by the Research Fund of Karadeniz Technical University, Project No: FBA-2019-7741 (Trabzon-Turkey).
dc.identifier.doi10.1007/s11243-022-00499-3
dc.identifier.endpage168
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue4-5
dc.identifier.scopus2-s2.0-85130189791
dc.identifier.scopusqualityQ2
dc.identifier.startpage157
dc.identifier.urihttps://doi.org/10.1007/s11243-022-00499-3
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25524
dc.identifier.volume47
dc.identifier.wosWOS:000796316600001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPhotodynamic Therapy
dc.subjectMetal-Free
dc.subjectZinc
dc.subjectBehavior
dc.titleAsymmetrically tetra-substituted phthalocyanine derivatives: synthesis, photophysical and photochemical properties
dc.typeArticle

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