Conducting semi-interpenetrating polymeric composites via the preparation of poly(aniline), poly(thiophene), and poly(pyrrole) polymers within superporous poly(acrylic acid) cryogels

dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.authoridDemirci, Şahin / 0000-0001-7083-1481
dc.contributor.authorŞahiner, Nurettin
dc.contributor.authorDemirci, Şahin
dc.date.accessioned2025-01-27T20:38:39Z
dc.date.available2025-01-27T20:38:39Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, a novel and special form of hydrogel known as cryogel with super and interconnected pore structures was synthesized as p(acrylic acid) (p(AAc)) cryogel by a cryopolymerization technique. Then, the superporous p(AAc) cryogels were used as template for the synthesis of conductive polymers such as poly(aniline) (p(An)), poly(thiophene) (p(Th)), and poly(pyrrole) (p(Py)). To the best of the authors' knowledge, this is the first study of its kind to report the synthesis of conductive polymers, p(An), p(Th), and p(Py), within the superporous network of cryogel. The synthesized p(AAc)/p(An), p(AAc)/p(Th), and p(AAc)/p(Py) conducting semi-interpenetrating polymeric network (semi-IPN) cryogel composites were characterized by using Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), and conductivity measurements. The conductivities of p(AAc)/p(An), p(AAc)/p(Th), and p(AAc)/p(Py) toward semi-IPN cryogels were measured as 2.2 x 10(-4) +/- 1 x 10(-5),32 x 10(-4) +/- 0.9 x 10(-5), and 3.2 x 10(-3) +/- 5 x 10(-4) S cm(-1), whereas the conductivity of bare p(AAc) cryogels was calculated to be about 3.2 x 10(-9) +/- 2.1 x 10(-10) S cm(-1). (C) 2016 Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey [214M130]
dc.description.sponsorshipThis study was supported by the Scientific and Technological Research Council of Turkey (214M130).
dc.identifier.doi10.1016/j.reactfunctpolym.2016.05.017
dc.identifier.endpage65
dc.identifier.issn1381-5148
dc.identifier.issn1873-166X
dc.identifier.scopus2-s2.0-84975159122
dc.identifier.scopusqualityQ1
dc.identifier.startpage60
dc.identifier.urihttps://doi.org/10.1016/j.reactfunctpolym.2016.05.017
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23693
dc.identifier.volume105
dc.identifier.wosWOS:000381322600006
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofReactive & Functional Polymers
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectSuperporous hydrogel/cryogels
dc.subjectConductive polymers
dc.subjectSemi-IPN cryogel composites
dc.subjectCo-network
dc.titleConducting semi-interpenetrating polymeric composites via the preparation of poly(aniline), poly(thiophene), and poly(pyrrole) polymers within superporous poly(acrylic acid) cryogels
dc.typeArticle

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