Synthesis, spectroscopic and thermal properties of Pt(II) complexes of some polydentate ligands

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorBaran, Yakup
dc.contributor.authorKaya, İsmet
dc.contributor.authorTürkyılmaz, Murat
dc.date.accessioned2025-01-27T20:56:22Z
dc.date.available2025-01-27T20:56:22Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe new tetradentate symmetrical (2R, 2'S)1,1'-piperazine-1,4-diyldipropane-2-thiol) (L-1), (2S)-1-[bis (2-aminoethyl) amino] propan-2-ol) (L-2), and 2-{(E)-[((1R, 2S)-2-{[(1Z)-(2-hydroxy phenyl)methylene]amino}cyclohexyl) imino] methyl} phenol (L-3) ligands were synthesized and characterized on the basis of FT-IR, H-1, C-13 NMR, EI mass, and elemental analysis. Three commercially available ligands, (2,2'-[ethane-1,2-diylbis(thio)] diethanol (L-4), 2,2'-dithiodiethanenamine (L-5), and (2,2-[ethane-1,2-diyldi(imino)] diethanol (L-6), were also studied. Pt(II) complexes were characterized by FTIR, elemental analysis and thermal methods. Thermal behaviors of these complexes were investigated in the range 10-1000 degrees C. Magnetic properties were also studied, and the all complexes were found to be diamagnetic. The structures consist of the monomeric units in which the Pt(II) atoms exhibit square planar geometry. N,N'-bis(salicylidene)-1,2-cyclohexane has been synthesized and characterized by X-ray single crystal diffraction measurement. The ligand crystallizes in monoclinic crystal system and space group, Cc.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [104T389]
dc.description.sponsorshipThe authors wish to thank the Scientific and Technological Research Council of Turkey (TUBITAK) for financial support (project no: 104T389) and BAP. Scientific Research Project of COMU.
dc.identifier.doi10.1007/s10973-011-1567-9
dc.identifier.endpage875
dc.identifier.issn1388-6150
dc.identifier.issue3
dc.identifier.scopus2-s2.0-85027942417
dc.identifier.scopusqualityQ1
dc.identifier.startpage869
dc.identifier.urihttps://doi.org/10.1007/s10973-011-1567-9
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26385
dc.identifier.volume107
dc.identifier.wosWOS:000302703400002
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPt(II)
dc.subjectPolydentate
dc.subjectFTIR
dc.subjectTG
dc.subjectNMR
dc.subjectThermal stability
dc.subjectX-ray
dc.titleSynthesis, spectroscopic and thermal properties of Pt(II) complexes of some polydentate ligands
dc.typeArticle

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