SYNTHESIS OF TETRANUCLEAR RUTHENIUM (II) COMPLEX OF PYRIDYLOXY-SUBSTITUTED 2,2?-DIOXYBIPHENYL-CYCLOTRIPHOSPHAZENE PLATFORM AND ITS CATALYTIC APPLICATION IN THE TRANSFER HYDROGENATION OF KETONES

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dc.authoriddayan, osman/0000-0002-0764-1965
dc.contributor.authorCirali, Digdem Erdener
dc.contributor.authorDayan, Osman
dc.date.accessioned2025-01-27T20:14:39Z
dc.date.available2025-01-27T20:14:39Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractCyclophosphazene was reacted with biphenyl-2,2'- diol to afford the N3P3Cl4(O2C12H8) (1). Then, pyridyloxy cyclophosphazene, spiro N3P3(O2C12H8)(O-C5H4N-3)(4) (2) was synthesized from the reaction of 3-hydroxy pyridine and compound 1. The reaction of 2 with [RuCl2(p-cymene)](2) afforded Ru(II) complex (3). The structures of the ligand and complex are characterized by elemental analysis, FT-IR, H-1-, and P-31-NMR spectroscopy. Ru(II) complex has been employed as catalysts for the transfer hydrogenation of acetophenone in the presence of KOH using 2-propanol as a hydrogen source. The complex has demonstrated good catalytic activity in transfer hydrogenation of ketones.
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [112T584]
dc.description.sponsorshipThe authors are grateful to the Scientific and Technical Research Council of Turkey (TUBITAK) for the financial support of this work, grant number 112T584.
dc.identifier.doi10.1080/10426507.2014.966190
dc.identifier.endpage1107
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue7
dc.identifier.scopus2-s2.0-84937823681
dc.identifier.scopusqualityQ3
dc.identifier.startpage1100
dc.identifier.urihttps://doi.org/10.1080/10426507.2014.966190
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21164
dc.identifier.volume190
dc.identifier.wosWOS:000359618400013
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofPhosphorus Sulfur and Silicon and The Related Elements
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCyclophosphazene
dc.subjectRu(II) complex
dc.subjectcatalyst
dc.subjectcatalytic activity
dc.titleSYNTHESIS OF TETRANUCLEAR RUTHENIUM (II) COMPLEX OF PYRIDYLOXY-SUBSTITUTED 2,2?-DIOXYBIPHENYL-CYCLOTRIPHOSPHAZENE PLATFORM AND ITS CATALYTIC APPLICATION IN THE TRANSFER HYDROGENATION OF KETONES
dc.typeArticle

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