Determination of photophysical, photochemical and spectroscopic properties of novel lead(II) phthalocyanines

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dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.authoridodabas, zafer/0000-0002-0647-0404
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorOzturk, Omer Faruk
dc.contributor.authorOdabas, Zafer
dc.date.accessioned2025-01-27T20:45:27Z
dc.date.available2025-01-27T20:45:27Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis study presents the synthesis and characterization of novel peripheral and non-peripheral tetra-2,6-dimethoxyphenoxy substituted lead(II) phthalocyanines. They were characterized by elemental analysis, IR, UV-vis, fluorescence, H-1 NMR, C-13 NMR and MALDI-TOF mass spectroscopic techniques, as well as thermogravimetric analysis. Their spectroscopic, photophysical and photochemical properties were studied in dimethylsulfoxide and compared with the above-mentioned properties of lead(II) phthalocyanines containing different substituents reported in the literature. Novel phthalocyanines can be good candidates as photosensitizers for photocatalytic reactions because they possess properties that are important for Type II mechanics, such as low photostability, sufficient singlet oxygen production, high solubility and non-aggregation behavior in commonly known organic solvents. (C) 2020 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipCanakkale Onsekiz Mart University, The Scientific Research Coordination Unit [FHD-2018-2768]
dc.description.sponsorshipThis work was supported by Canakkale Onsekiz Mart University, The Scientific Research Coordination Unit, Project number: FHD-2018-2768.
dc.identifier.doi10.1016/j.poly.2020.114480
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85081218398
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.poly.2020.114480
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24576
dc.identifier.volume182
dc.identifier.wosWOS:000528267000008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPhthalocyanine
dc.subjectHeavy metal
dc.subjectSinglet oxygen
dc.subjectLow photostability
dc.titleDetermination of photophysical, photochemical and spectroscopic properties of novel lead(II) phthalocyanines
dc.typeArticle

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