Synthesis and spectroscopic properties of geminal-bis(tert-butylamino)cyclotriphosphazenes obtained by the reaction of Spiro and ansa phenoxycyclotriphosphazenes with the tert-butylamine and the crystal structure of 4,4?-bis(tert-butylamino)-2,6?,6?,10-tetrachloro-4?,4?,6?,6?-tetrahydrospyro[12H-dibenzo[d,g]- (1,3,2]dioxaphosphocin-6,2??5-[1,3,5,2,4,6]-triazaphosphorine]
dc.contributor.author | Erdener, Digdem | |
dc.contributor.author | Yıldız, Mustafa | |
dc.contributor.author | Unver, Huseyin | |
dc.contributor.author | Iskeleli, Nazan Ocak | |
dc.contributor.author | Durlu, Tahsin Nuri | |
dc.date.accessioned | 2025-01-27T20:50:31Z | |
dc.date.available | 2025-01-27T20:50:31Z | |
dc.date.issued | 2011 | |
dc.department | Çanakkale Onsekiz Mart Üniversitesi | |
dc.description.abstract | The condensation reactions of partly substituted spiro and ansa phcnoxycyclotriphosphazenes 1 and 2 with tert-butylamine produce disubstituted geminal-bis(tert-butylamino)phenoxycyclotriphosphazene derivatives (3 and 4). The structures of these compounds were characterized by elemental analysis, and IR, H-1-, C-13-, P-31-NMR and mass spectroscopic techniques. Compound 3 was also examined by X-ray crystallography and found to be crystallized in the monoclinic space group P2(1)/n with the unit cell parameters: a = = 10.842(4), b = 9.375(5), c = 29.104(11) angstrom, beta = 99.25(3), V= 2920(2) angstrom(3), D-x = 1.404 g cm(-3). | |
dc.description.sponsorship | Scientific and Technical Research Council of Turkey (TUBITAK) [106T108] | |
dc.description.sponsorship | The authors are grateful to the Scientific and Technical Research Council of Turkey (TUBITAK) for the financial support of this work, grant number 106T108. | |
dc.identifier.doi | 10.2298/JSC100722070E | |
dc.identifier.endpage | 840 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.issue | 6 | |
dc.identifier.scopus | 2-s2.0-79959420504 | |
dc.identifier.scopusquality | Q3 | |
dc.identifier.startpage | 831 | |
dc.identifier.uri | https://doi.org/10.2298/JSC100722070E | |
dc.identifier.uri | https://hdl.handle.net/20.500.12428/25512 | |
dc.identifier.volume | 76 | |
dc.identifier.wos | WOS:000292714000003 | |
dc.identifier.wosquality | Q3 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | |
dc.publisher | Serbian Chemical Soc | |
dc.relation.ispartof | Journal of The Serbian Chemical Society | |
dc.relation.publicationcategory | info:eu-repo/semantics/openAccess | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.snmz | KA_WoS_20250125 | |
dc.subject | phenoxyphosphazenes | |
dc.subject | spectroscopy | |
dc.subject | spiro | |
dc.subject | ansa | |
dc.subject | crystal structure | |
dc.title | Synthesis and spectroscopic properties of geminal-bis(tert-butylamino)cyclotriphosphazenes obtained by the reaction of Spiro and ansa phenoxycyclotriphosphazenes with the tert-butylamine and the crystal structure of 4,4?-bis(tert-butylamino)-2,6?,6?,10-tetrachloro-4?,4?,6?,6?-tetrahydrospyro[12H-dibenzo[d,g]- (1,3,2]dioxaphosphocin-6,2??5-[1,3,5,2,4,6]-triazaphosphorine] | |
dc.type | Article |