Synthesis and spectroscopic properties of geminal-bis(tert-butylamino)cyclotriphosphazenes obtained by the reaction of Spiro and ansa phenoxycyclotriphosphazenes with the tert-butylamine and the crystal structure of 4,4?-bis(tert-butylamino)-2,6?,6?,10-tetrachloro-4?,4?,6?,6?-tetrahydrospyro[12H-dibenzo[d,g]- (1,3,2]dioxaphosphocin-6,2??5-[1,3,5,2,4,6]-triazaphosphorine]

Basit Öğe Kaydı
dc.contributor.authorErdener, Digdem
dc.contributor.authorYıldız, Mustafa
dc.contributor.authorUnver, Huseyin
dc.contributor.authorIskeleli, Nazan Ocak
dc.contributor.authorDurlu, Tahsin Nuri
dc.date.accessioned2025-01-27T20:50:31Z
dc.date.available2025-01-27T20:50:31Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe condensation reactions of partly substituted spiro and ansa phcnoxycyclotriphosphazenes 1 and 2 with tert-butylamine produce disubstituted geminal-bis(tert-butylamino)phenoxycyclotriphosphazene derivatives (3 and 4). The structures of these compounds were characterized by elemental analysis, and IR, H-1-, C-13-, P-31-NMR and mass spectroscopic techniques. Compound 3 was also examined by X-ray crystallography and found to be crystallized in the monoclinic space group P2(1)/n with the unit cell parameters: a = = 10.842(4), b = 9.375(5), c = 29.104(11) angstrom, beta = 99.25(3), V= 2920(2) angstrom(3), D-x = 1.404 g cm(-3).
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [106T108]
dc.description.sponsorshipThe authors are grateful to the Scientific and Technical Research Council of Turkey (TUBITAK) for the financial support of this work, grant number 106T108.
dc.identifier.doi10.2298/JSC100722070E
dc.identifier.endpage840
dc.identifier.issn0352-5139
dc.identifier.issue6
dc.identifier.scopus2-s2.0-79959420504
dc.identifier.scopusqualityQ3
dc.identifier.startpage831
dc.identifier.urihttps://doi.org/10.2298/JSC100722070E
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25512
dc.identifier.volume76
dc.identifier.wosWOS:000292714000003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSerbian Chemical Soc
dc.relation.ispartofJournal of The Serbian Chemical Society
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectphenoxyphosphazenes
dc.subjectspectroscopy
dc.subjectspiro
dc.subjectansa
dc.subjectcrystal structure
dc.titleSynthesis and spectroscopic properties of geminal-bis(tert-butylamino)cyclotriphosphazenes obtained by the reaction of Spiro and ansa phenoxycyclotriphosphazenes with the tert-butylamine and the crystal structure of 4,4?-bis(tert-butylamino)-2,6?,6?,10-tetrachloro-4?,4?,6?,6?-tetrahydrospyro[12H-dibenzo[d,g]- (1,3,2]dioxaphosphocin-6,2??5-[1,3,5,2,4,6]-triazaphosphorine]
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu