Spectroscopic Studies and Crystal Structure of Four-Coordinate Manganese(II) Chloride Complex

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dc.authoridUnver, Huseyin/0000-0003-3968-4385
dc.authoridOzay, Hava/0000-0002-4184-7801
dc.contributor.authorOzay, Hava
dc.contributor.authorYıldız, Mustafa
dc.contributor.authorUnver, Huseyin
dc.contributor.authorIskeleli, Nazan Ocak
dc.date.accessioned2025-01-27T20:56:20Z
dc.date.available2025-01-27T20:56:20Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractHigh-spin new, manganese-(II) L2MnCl2, complex has been synthesized and its structure was elucidated by using elemental analysis, FT-IR, DTA-TG, H-1-NMR, C-13-NMR, and UV-Visible spectroscopic techniques. The structure of the compound has also been examined crystallographically. The title compound crystallizes in the triclinic space group P-1, with unit cell parameters: a = 11.354(1), b = 11.868(1), c = 12.080(1) angstrom, V = 1548.9(1) angstrom(3), D-x = 1.270 g.cm(-3), and Z = 2, respectively. The Mn atom was tetra-coordinated to form a distorted tetrahedral geometry by two oxygen atoms of L-2 and two chloride atoms of MnCl2 center dot 4H(2)O in the complex.
dc.description.sponsorshipCanakkale Onsekiz Mart University Grants Commission [2011/004]
dc.description.sponsorshipThe authors thank Canakkale Onsekiz Mart University Grants Commission for a research grant (Project Number: 2011/004).
dc.identifier.doi10.1080/15533174.2011.618756
dc.identifier.endpage877
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue6
dc.identifier.scopus2-s2.0-84864044122
dc.identifier.scopusqualityN/A
dc.identifier.startpage872
dc.identifier.urihttps://doi.org/10.1080/15533174.2011.618756
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26376
dc.identifier.volume42
dc.identifier.wosWOS:000306319300017
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectcrystal structure
dc.subjectDTA-TG
dc.subjectfour-coordinated manganese(II)
dc.subjectNMR
dc.subjectspectroscopic studies
dc.titleSpectroscopic Studies and Crystal Structure of Four-Coordinate Manganese(II) Chloride Complex
dc.typeArticle

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