Highly effective palladium nanocatalyst supported in polymeric networks for the catalytic hydrogen generation from borane-morpholine complex

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dc.authoridOzay, Hava/0000-0002-4184-7801
dc.contributor.authorOzay, Hava
dc.contributor.authorTercan, Melek
dc.contributor.authorÖzay, Özgür
dc.contributor.authorIlgin, Pinar
dc.date.accessioned2025-01-27T20:29:18Z
dc.date.available2025-01-27T20:29:18Z
dc.date.issued2022
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis study describes the synthesis of Pd-0 nanoparticles supported in hydrogel networks (SPVI@Pd) and their catalytic activity for the borane-morpholine complex (MB) hydrolysis reaction. In this respect, while our study is one of the limited number of studies reported for the catalytic hydrolysis of MB, it is the first study in which Pd-0 nanoparticles supported in hydrogel networks were used in the catalytic hydrolysis of MB. The synthesized Pd-0 nanoparticles were characterized using structural and morphological characterization techniques and as a result of these analyses, the sizes of Pd-0 nanoparticles were determined average as 7.01 +/- 1.90 nm. The E-a value and the turnover frequency (TOF) value at 303 K for the SPVI@Pd-3.0 catalyzed MB hydrolysis reaction were determined as 49.46 kJ/mol and 187.74 mol(H2)center dot mol(pd)(-1).h(-1). It was also observed that the SPVI@Pd-3.0 catalyst had good catalytic activity even after eight cycles.
dc.identifier.doi10.1002/slct.202203874
dc.identifier.issn2365-6549
dc.identifier.issue45
dc.identifier.scopus2-s2.0-85143340009
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1002/slct.202203874
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22901
dc.identifier.volume7
dc.identifier.wosWOS:000895013300049
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChemistryselect
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectHeterogeneous catalysis
dc.subjectHydrogen
dc.subjectNanotechnology
dc.subjectPalladium
dc.titleHighly effective palladium nanocatalyst supported in polymeric networks for the catalytic hydrogen generation from borane-morpholine complex
dc.typeArticle

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