Esterified porphyrazine complexes: Synthesis, characterization, aggregation behavior, and theoretical study

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dc.contributor.authorGonca, Ergun
dc.contributor.authorOzpinar, Celal
dc.date.accessioned2025-01-27T20:45:27Z
dc.date.available2025-01-27T20:45:27Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractMagnesium porphyrazine having eight 5-hydroxypentylthio groups at the peripheral positions, was synthesized from 2,3-bis(5-hydroxypentylthio) maleonitrile. By the esterification reaction of octakis(5-hydroxypentylthio) porphyrazinato] Mg(II) with 3,4,5-trimethoxybenzoic acid in dicyclohexylcarbodiimide and toluene-p-sulfonic acid, esterified MgPz appending [5-thiopentyl 2-methoxy-4,6-bis(trifluoromethyl) benzoate] substituent was obtained. Further reaction of the metal-free porphyrazine with Co(II), Cu(II), Zn(II), and Fe(II) acetates have produced the metallo-porphyrazines. By reacting FePzCl with pyridine or pyrazine, the monomeric bis-axial and the oligomeric complexes were synthesized as the novel stable complexes, respectively. Their characterizations were performed by using elemental analysis, FT-IR, H-1-NMR, C-13-NMR, mass and UV-Vis spectral data. The aggregation investigations carried out in different concentrations indicate that 3,4,5-trimethoxybenzyloxy-substituted porphyrazine compounds do not have any aggregation behavior in different concentrations. Quantum chemical computations were also done to the structural and electronic properties of target compounds.
dc.description.sponsorshipScientific Research Fund of Canakkale Onsekiz Mart University [FBA-2014-238]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of Canakkale Onsekiz Mart University under the Project No. FBA-2014-238.
dc.identifier.doi10.1080/10601325.2017.1313130
dc.identifier.endpage393
dc.identifier.issn1060-1325
dc.identifier.issn1520-5738
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85018309803
dc.identifier.scopusqualityQ2
dc.identifier.startpage382
dc.identifier.urihttps://doi.org/10.1080/10601325.2017.1313130
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24573
dc.identifier.volume54
dc.identifier.wosWOS:000400325000004
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofJournal of Macromolecular Science Part A-Pure and Applied Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectEsterification
dc.subjectiron
dc.subjectoligomeric complex
dc.subjectPM6
dc.subjectporphyrazine
dc.subject3,4,5-trimethoxybenzoic acid
dc.titleEsterified porphyrazine complexes: Synthesis, characterization, aggregation behavior, and theoretical study
dc.typeArticle

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