Synthesis, characterization and thermal study of some tetradentate Schiff base transition metal complexes

dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorDoğan, Fatih
dc.contributor.authorUlusoy, Mahmut
dc.contributor.authorOzturk, Omer F.
dc.contributor.authorKaya, İsmet
dc.contributor.authorSalih, Bekir
dc.date.accessioned2025-01-27T20:28:59Z
dc.date.available2025-01-27T20:28:59Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractSeveral mononuclear Co(II), Ni(II), Cu(II), and Fe(II) complexes of tetradentate salpren-type diimine, obtained from 3,5-di-tert-butyl-2-hydroxybenzaldehyde and 1,3-diaminopropane have been prepared and characterized by analytical, spectroscopic (FT-IR, UV-VIS) techniques, magnetic susceptibility measurements and thermogravimetric analyses (TG). The thermodynamic and thermal properties of complexes have been investigated. For further characterization Direct Insertion Probe-Mass Spectrometry (DIP-MS) was used and the fragmentation pattern and also stability of the ions were evaluated. The characterization of the end products of the decomposition was achieved by X-ray diffraction. The thermal stabilities of metal complexes of N,N'-bis(3,5-di-t-butylsalicylidene)-1,3-propanediamine ligand (L) were found as Ni(II) > Cu(II) > Co(II) > Fe(II).
dc.identifier.doi10.1007/s10973-009-0205-2
dc.identifier.endpage792
dc.identifier.issn1388-6150
dc.identifier.issn1588-2926
dc.identifier.issue3
dc.identifier.scopus2-s2.0-75149163248
dc.identifier.scopusqualityQ1
dc.identifier.startpage785
dc.identifier.urihttps://doi.org/10.1007/s10973-009-0205-2
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22764
dc.identifier.volume98
dc.identifier.wosWOS:000272800700027
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectActivation energy
dc.subjectSterically hindered diimine
dc.subjectThermal decomposition
dc.subjectTransition metal complexes
dc.titleSynthesis, characterization and thermal study of some tetradentate Schiff base transition metal complexes
dc.typeArticle

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