Synthesis, characterization and thermal study of some tetradentate Schiff base transition metal complexes
dc.authorid | Kaya, Ismet/0000-0002-9813-2962 | |
dc.contributor.author | Doğan, Fatih | |
dc.contributor.author | Ulusoy, Mahmut | |
dc.contributor.author | Ozturk, Omer F. | |
dc.contributor.author | Kaya, İsmet | |
dc.contributor.author | Salih, Bekir | |
dc.date.accessioned | 2025-01-27T20:28:59Z | |
dc.date.available | 2025-01-27T20:28:59Z | |
dc.date.issued | 2009 | |
dc.department | Çanakkale Onsekiz Mart Üniversitesi | |
dc.description.abstract | Several mononuclear Co(II), Ni(II), Cu(II), and Fe(II) complexes of tetradentate salpren-type diimine, obtained from 3,5-di-tert-butyl-2-hydroxybenzaldehyde and 1,3-diaminopropane have been prepared and characterized by analytical, spectroscopic (FT-IR, UV-VIS) techniques, magnetic susceptibility measurements and thermogravimetric analyses (TG). The thermodynamic and thermal properties of complexes have been investigated. For further characterization Direct Insertion Probe-Mass Spectrometry (DIP-MS) was used and the fragmentation pattern and also stability of the ions were evaluated. The characterization of the end products of the decomposition was achieved by X-ray diffraction. The thermal stabilities of metal complexes of N,N'-bis(3,5-di-t-butylsalicylidene)-1,3-propanediamine ligand (L) were found as Ni(II) > Cu(II) > Co(II) > Fe(II). | |
dc.identifier.doi | 10.1007/s10973-009-0205-2 | |
dc.identifier.endpage | 792 | |
dc.identifier.issn | 1388-6150 | |
dc.identifier.issn | 1588-2926 | |
dc.identifier.issue | 3 | |
dc.identifier.scopus | 2-s2.0-75149163248 | |
dc.identifier.scopusquality | Q1 | |
dc.identifier.startpage | 785 | |
dc.identifier.uri | https://doi.org/10.1007/s10973-009-0205-2 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12428/22764 | |
dc.identifier.volume | 98 | |
dc.identifier.wos | WOS:000272800700027 | |
dc.identifier.wosquality | Q3 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | |
dc.publisher | Springer | |
dc.relation.ispartof | Journal of Thermal Analysis and Calorimetry | |
dc.relation.publicationcategory | info:eu-repo/semantics/openAccess | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.snmz | KA_WoS_20250125 | |
dc.subject | Activation energy | |
dc.subject | Sterically hindered diimine | |
dc.subject | Thermal decomposition | |
dc.subject | Transition metal complexes | |
dc.title | Synthesis, characterization and thermal study of some tetradentate Schiff base transition metal complexes | |
dc.type | Article |