Synthesis, characterization and thermal study of some tetradentate Schiff base transition metal complexes

Basit Öğe Kaydı
dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorDoğan, Fatih
dc.contributor.authorUlusoy, Mahmut
dc.contributor.authorOzturk, Omer F.
dc.contributor.authorKaya, İsmet
dc.contributor.authorSalih, Bekir
dc.date.accessioned2025-01-27T20:28:59Z
dc.date.available2025-01-27T20:28:59Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractSeveral mononuclear Co(II), Ni(II), Cu(II), and Fe(II) complexes of tetradentate salpren-type diimine, obtained from 3,5-di-tert-butyl-2-hydroxybenzaldehyde and 1,3-diaminopropane have been prepared and characterized by analytical, spectroscopic (FT-IR, UV-VIS) techniques, magnetic susceptibility measurements and thermogravimetric analyses (TG). The thermodynamic and thermal properties of complexes have been investigated. For further characterization Direct Insertion Probe-Mass Spectrometry (DIP-MS) was used and the fragmentation pattern and also stability of the ions were evaluated. The characterization of the end products of the decomposition was achieved by X-ray diffraction. The thermal stabilities of metal complexes of N,N'-bis(3,5-di-t-butylsalicylidene)-1,3-propanediamine ligand (L) were found as Ni(II) > Cu(II) > Co(II) > Fe(II).
dc.identifier.doi10.1007/s10973-009-0205-2
dc.identifier.endpage792
dc.identifier.issn1388-6150
dc.identifier.issn1588-2926
dc.identifier.issue3
dc.identifier.scopus2-s2.0-75149163248
dc.identifier.scopusqualityQ1
dc.identifier.startpage785
dc.identifier.urihttps://doi.org/10.1007/s10973-009-0205-2
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22764
dc.identifier.volume98
dc.identifier.wosWOS:000272800700027
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectActivation energy
dc.subjectSterically hindered diimine
dc.subjectThermal decomposition
dc.subjectTransition metal complexes
dc.titleSynthesis, characterization and thermal study of some tetradentate Schiff base transition metal complexes
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu