Synthesis and structural X-ray analysis of 1,1?-(naphthalene-1,8-diyl)-3,3?-dibenzoyl-bisthiourea and its use as anion-binding receptor

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dc.authoridKazak, Canan/0000-0003-2475-8775
dc.authoridARSLAN, N. Burcu/0000-0002-1880-1047
dc.contributor.authorAydin, Fatma
dc.contributor.authorTunoglu, Nazan
dc.contributor.authorAykac, Dogan
dc.contributor.authorArslan, Nahide Burcu
dc.contributor.authorKazak, Canan
dc.date.accessioned2025-01-27T20:24:23Z
dc.date.available2025-01-27T20:24:23Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA novel artificial receptor, 1,1'-(naphthalene-1,8-diyl)-3,3'-dibenzoyl-bisthiourea, based on a 1,8-naphthalene skeleton bearing bisthiourea groups was prepared and characterized by IR and H-1-NMR, C-13-NMR, and MS spectroscopic techniques. The compound proved to be an efficient and selective naked-eye detector for the fluoride, cyanide, and hydroxide ions in DMSO. The crystal structure of the title compound was examined by using X-ray crystallographic techniques and found to be crystallized in the monoclinic space group P - 1 with the unit cell parameters: a = 8.1556(8) angstrom, b = 12.0127(11) angstrom, c = 13.2081(11) angstrom, alpha = 109.510(7)degrees, beta = 95.390(7)degrees, gamma = 103.660(7)degrees, Z = 2. The intramolecular N-H center dot center dot center dot O hydrogen bonding interactions between the N-H and the oxygen atom of C=O groups support a 1,1'-(naphthalene-1,8-diyl)3,3'-dibenzoyl-bisthiourea framework. Moreover, the combinations of N-H center dot center dot center dot S bonds produce R-2(2) (8) rings.
dc.description.sponsorshipCanakkale Onsekiz Mart University Grants Commission [2008/35]
dc.description.sponsorshipThe financial support from Canakkale Onsekiz Mart University Grants Commission (Project Number: 2008/35) is gratefully acknowledged. We thank Hacettepe University Department of Chemistry for the 1H-NMR titration experiments and mass analyses.
dc.identifier.doi10.3906/kim-1201-12
dc.identifier.endpage777
dc.identifier.issn1300-0527
dc.identifier.issue5
dc.identifier.scopus2-s2.0-84870791527
dc.identifier.scopusqualityQ3
dc.identifier.startpage764
dc.identifier.urihttps://doi.org/10.3906/kim-1201-12
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22190
dc.identifier.volume36
dc.identifier.wosWOS:000311947000012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subject1,1 '-(Naphthalene-1,8-diyl)-3,3 '-dibenzoyl-bisthiourea
dc.subjectanion-binding receptor
dc.subjectcrystal structure
dc.subjectbisthiourea
dc.titleSynthesis and structural X-ray analysis of 1,1?-(naphthalene-1,8-diyl)-3,3?-dibenzoyl-bisthiourea and its use as anion-binding receptor
dc.typeArticle

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