Synthesis and characterization of chelate polymers containing etheric diphenyl ring in the backbone: thermal, optical, electrochemical, and morphological properties

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorAydın, Aysel
dc.date.accessioned2025-01-27T20:48:00Z
dc.date.available2025-01-27T20:48:00Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA novel Schiff base, 4-bromo-2-[(2-[(5-bromo-2-hydroxyphenyl)methylene]amino-5-nitrophenyl)iminomethyl]phenol (M1) was synthesized from the reaction of 5-brom-salicylaldehyde with 4-nitro-o-phenylenediamine. Schiff base-metal complex was synthesized from the reaction of 4-bromo-2-[(2-[(5-bromo-2-hydroxyphenyl)methylene]amino-5-nitrophenyl) iminomethyl] phenol (M1) with copper (II) acetate monohydrate [(CH(3)COO)(2) Cu center dot H(2)O] salt. Poly-(M1-Cu-TDP) was synthesized from the reaction of M1-Cu with 4,4'-dithiodiphenol (TDP). Poly(M1-Cu-PDP) was synthesized from the reaction of M1-Cu with 4,4'-propane-2,2-diyldiphenol (PDP). Poly(M1-Cu-HDP) was synthesized from the reaction of M1-Cu with 4,4'-(1,1,1,3,3,3-hexafluoropropane-2,2-di-yl) diphenol (HDP). The structures of the synthesized monomer and chelate polymers were confirmed by FT-IR, UV-Vis, (1)H-and (13)C-NMR, and elemental analysis. The characterization was made by TGA-DTA, DSC, size exclusion chromatography, cyclic voltammetry, and solubility tests. Also, surface morphologies of chelate polymers were investigated by scanning electron microscope. Copyright (C) 2009 John Wiley & Sons, Ltd.
dc.identifier.doi10.1002/pat.1601
dc.identifier.endpage961
dc.identifier.issn1042-7147
dc.identifier.issue6
dc.identifier.scopus2-s2.0-79955972275
dc.identifier.scopusqualityQ2
dc.identifier.startpage951
dc.identifier.urihttps://doi.org/10.1002/pat.1601
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25108
dc.identifier.volume22
dc.identifier.wosWOS:000290631400024
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-Blackwell
dc.relation.ispartofPolymers For Advanced Technologies
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectchelate polymers
dc.subjectthermal analysis
dc.subjectelectrochemical and optical band gaps
dc.titleSynthesis and characterization of chelate polymers containing etheric diphenyl ring in the backbone: thermal, optical, electrochemical, and morphological properties
dc.typeArticle

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