Adsorption of Nitrogen Dioxide on Nitrogen-Enriched Activated Carbons

dc.authoridCielecka-Piontek, Judyta/0000-0003-0891-5419
dc.authoridYilmaz, Selehattin/0000-0003-4607-3523
dc.authoridBazan-Wozniak, Aleksandra/0000-0002-2365-8919
dc.contributor.authorBazan-Wozniak, Aleksandra
dc.contributor.authorNosal-Wiercinska, Agnieszka
dc.contributor.authorCielecka-Piontek, Judyta
dc.contributor.authorYilmaz, Selehattin
dc.contributor.authorPietrzak, Robert
dc.date.accessioned2025-01-27T21:19:48Z
dc.date.available2025-01-27T21:19:48Z
dc.date.issued2024
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe aim of this study was to obtain nitrogen-enriched activated carbons from orthocoking coal. The initial material was subjected to a demineralisation process. The demineralised precursor was pyrolysed at 500 degrees C and then activated with sodium hydroxide at 800 degrees C. Activated carbon adsorbents were subjected to the process of ammoxidation using a mixture of ammonia and air at two different temperature variants (300 and 350 degrees C). Nitrogen introduction was carried out on stages of demineralised precursor, pyrolysis product, and oxidising activator. The elemental composition, acid-base properties, and textural parameters of the obtained carbon adsorbents were determined. The activated carbons were investigated for their ability to remove nitrogen dioxide. The results demonstrated that the ammoxidation process incorporates new nitrogen-based functional groups into the activated carbon structure. Simultaneously, the ammoxidation process modified the acid-base characteristics of the surface and negatively affected the textural parameters of the resulting adsorbents. Furthermore, the study showed that all of the obtained carbon adsorbents exhibited a distinct microporous texture. Adsorption tests were carried out against NO2 and showed that the carbon adsorbents obtained were highly effective in removing this gaseous pollutant. The best sorption capacity towards NO2 was 23.5 mg/g under dry conditions and 75.0 mg/g under wet conditions.
dc.identifier.doi10.3390/ijms25084421
dc.identifier.issn1661-6596
dc.identifier.issn1422-0067
dc.identifier.issue8
dc.identifier.pmid38674006
dc.identifier.scopus2-s2.0-85191362739
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.3390/ijms25084421
dc.identifier.urihttps://hdl.handle.net/20.500.12428/28740
dc.identifier.volume25
dc.identifier.wosWOS:001211405200001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherMdpi
dc.relation.ispartofInternational Journal of Molecular Sciences
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectactivated carbon
dc.subjectchemical activation
dc.subjectammoxidation
dc.subjectphysiochemical properties
dc.subjectNO2 adsorption
dc.titleAdsorption of Nitrogen Dioxide on Nitrogen-Enriched Activated Carbons
dc.typeArticle

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