A neutral state colorless phosphazene/carbazole hybride dendron and its electrochromic device application

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dc.authoridOzay, Hava/0000-0002-4184-7801
dc.authoridKoyuncu, Sermet/0000-0001-8352-8326
dc.contributor.authorSezgin, Meryem
dc.contributor.authorÖzay, Özgür
dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorOzay, Hava
dc.contributor.authorKoyuncu, Fatma Baycan
dc.date.accessioned2025-01-27T20:41:46Z
dc.date.available2025-01-27T20:41:46Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this work, a new phosphazene/carbazole hybride dendron (PC) was synthesized and then directly coated onto ITO glass surface to provide a dendritic polymer network, poly-(PC), by using potentiodynamic electrochemical process. Structure of dendron was identified by FT-IR, H-1 and P-31 NMR, and also TOF-MS analyses. The optical and electrochemical properties of PC and its electrochemical crosslinked product were investigated by using UV-vis absorption, fluorescence and CV techniques. A neutral, colorless electrochromic device was constructed in the sandwich configuration [indium tin oxide (ITO)coated glass/anodically coloring material (poly-(PC))//gel electrolyte//cathodically coloring material (PEDOT)/ITO-coated glass] and revealed a short response time (about 0.5 s), high coloration efficiency (981 cm(2) C-1) and high redox stability. (C) 2015 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.cej.2015.03.134
dc.identifier.endpage289
dc.identifier.issn1385-8947
dc.identifier.issn1873-3212
dc.identifier.scopus2-s2.0-84927728831
dc.identifier.scopusqualityQ1
dc.identifier.startpage282
dc.identifier.urihttps://doi.org/10.1016/j.cej.2015.03.134
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24234
dc.identifier.volume274
dc.identifier.wosWOS:000355496300030
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofChemical Engineering Journal
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectElectrochromic device
dc.subjectPhosphazene
dc.subjectCarbazole
dc.subjectDendron
dc.titleA neutral state colorless phosphazene/carbazole hybride dendron and its electrochromic device application
dc.typeArticle

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