Synthesis of Two Novel Aroyl Thioureas and Their Use as Anion Binding Receptors

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dc.contributor.authorAydin, Fatma
dc.contributor.authorTunoglu, Nazan
dc.contributor.authorAykac, Dogan
dc.date.accessioned2025-01-27T20:54:21Z
dc.date.available2025-01-27T20:54:21Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractNew aroyl thioureas; N-nicotinoyl-N'-(4-nitrophenyl) thiourea (3a) and N-nicotinoyl-N'-(2-nitrophenyl) thiourea (3b) were synthesized and studied as anion-binding receptors. Upon adding tetrabutyl ammonium halides (fluoride, chloride bromide and iodide), cyanide and hydroxide ions to their solutions in DMSO respectively, the colour of the solutions has shown striking changes from pale yellow to brillant yellow or red. The binding effects of the anions were investigated by UV-VIS spectroscopic method and H-1 NMR titrations.
dc.description.sponsorshipCanakkale Onsekiz Mart University Grants Commission [2008/35]
dc.description.sponsorshipThe financial support from Canakkale Onsekiz Mart University Grants Commission (Project Number: 2008/35) was gratefully acknowledged. The authors also thank Hacettepe University, Department of Chemistry for 1H NMR titration experiments and MS analyses.
dc.identifier.doi10.14233/ajchem.2013.13396
dc.identifier.endpage2458
dc.identifier.issn0970-7077
dc.identifier.issn0975-427X
dc.identifier.issue5
dc.identifier.scopus2-s2.0-84875092117
dc.identifier.scopusqualityQ4
dc.identifier.startpage2455
dc.identifier.urihttps://doi.org/10.14233/ajchem.2013.13396
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26051
dc.identifier.volume25
dc.identifier.wosWOS:000317245800023
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAsian Journal Of Chemistry
dc.relation.ispartofAsian Journal of Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectN-Substituted thiourea
dc.subjectAnion coordination
dc.subjectUV-VIS and H-1 NMR titrations
dc.titleSynthesis of Two Novel Aroyl Thioureas and Their Use as Anion Binding Receptors
dc.typeArticle

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